UNITED24 - Make a charitable donation in support of Ukraine!

Weapons of Mass Destruction (WMD)

Previous PageTable Of ContentsList Of FiguresList Of TablesNext Page

Appendix F

F.1 Introduction


The potential for facility Accidents and the magnitude of their effects are important factors in evaluating the waste management alternatives addressed in this environmental impact statement (eis). This appendix presents accident information related to the facilities that are or could be involved with the waste management alternatives. By using postulated accident scenarios associated with the existing and proposed waste processing, storage, and disposal facilities, this appendix describes the potential consequences and risks of waste management activities to workers, the public, and the environment.

Postulated accident scenarios were developed for each waste type under the alternatives evaluated in this eis. This appendix considers the five waste types generated and managed at SRS: high-level radioactive waste, low-level radioactive waste, hazardous waste, mixed waste, and transuranic waste.


F.2 General Accident Information


An accident, as discussed in this appendix, is an inadvertent release of radioactive or hazardous material from its confinement to the environment resulting in serious physical injury or substantial property damage. Initiating events are typically defined in three broad categories:

- External initiators originate outside the facility and potentially affect the ability of the facility to keep the material confined. Examples of external initiators are aircraft crashes, nearby explosions, and hazardous chemical releases from nearby facilities that could affect the ability of personnel to properly manage the radioactive/hazardous materials facility and its contents.

- Internal initiators originate within a facility and are usually the result of facility operation. Examples of internal initiators are equipment failures and human error.

- Natural phenomena initiators are natural occurrences such as floods, tornadoes, and earthquakes.

Sabotage and terrorist activities (i.e., intentional human initiators) could be either external or internal initiators.

For this appendix, "facility Accidents " are accidents associated with facilities that support or are involved in the treatment, storage, or disposal of the five waste types identified in Section F.1. Accident scenarios associated with waste management activities performed at a specific facility are also considered "facility accidents."

The probability of an accident (i.e., annual frequency) and its consequences depend on the type of initiator(s), how often that initiator occurs, and the frequency with which the resulting chain of events would lead to a release of material. Potential Accidents (and their effects) are grouped into four categories -- anticipated accidents, unlikely accidents, extremely unlikely accidents, and beyond extremely unlikely accidents -- based on their estimated annual frequency. Table F-1 lists, in decreasing order, these accident categories and their corresponding frequency ranges. For example, if an earthquake of sufficient magnitude to cause a release of material to the environment is expected to occur once every 5,000 years, the frequency for this accident is presented as 1 in 5,000, or 0.0002 (expressed as 2.0E-04; see Acronyms, Abbreviations, and the Use of Scientific Notation) per year (i.e., it is an unlikely accident per Table F­1).
DOE does not consider events that are expected to occur less often than once every 10 years to be "Accidents ." This does not imply that undesirable releases of radioactive or hazardous materials cannot occur more than once every 10 years. However, events with a probability of occurring more than once every 10 years are considered "abnormal events" because their occurrence is expected during the life of the facility, and they usually do not result in substantial onsite or offsite consequences. Potential effects from these releases are addressed in the Occupational and Public Health sections of this eis. DOE implements physical and administrative controls on facility operations and activities to minimize the likelihood and impacts of such events. Personnel are trained and drilled on how to respond to and mitigate potential releases from abnormal events.

Table F-2 presents the relative risk of a one-in-a-million chance of dying from several different common-place activities (WSRC 1994a).


Table F-1. Accident frequency categories.




Frequency category
Frequency range
(Accidents per year)
Anticipated accidentsaccidentsOccurs between once in 10 years and once in 100 years
Unlikely accidentsaccidentsOccurs between once in 100 years and once in 10,000 years
Extremely unlikely accidentsaccidentsOccurs between once in 10,000 years and once in 1,000,000 years
Beyond extremely unlikely accidentsaccidents Occurs less than once in 1,000,000 years

a. DOE (1994a).



Table F-2. Activities that have a one-in-one-million chance of causing death.


Smoking 1.4 cigarettes (lung cancer)
Eating 40 tablespoons of peanut butter (aflatoxins)
Eating 100 charcoal-broiled steaks (carcinogens from charcoal broiling)
Spending 2 days in New York City (air pollution)
Driving 40 miles in a car (accident)
Flying 2,500 miles in a jet (accident)
Canoeing for 6 minutes (accident)


F.3 Historic Perspective


Many of the actions proposed under the waste management alternatives considered in this eis are continuations or variations of past SRS operations. DOE studies historic nonroutine events, abnormal occurrences, and Accidents so similar events in present or future operations can be minimized or prevented. Historic events at facilities in the DOE complex are documented and tracked in two different computer data bases maintained by the U.S. Department of Energy (DOE) Office of Nuclear Energy at the Idaho National Engineering Laboratory: the Occurrence Reporting and Processing System (ORPS) and the Safety Performance Measurement System (SPMS). In addition, Savannah River Site (SRS) maintains computer data bases, such as the Waste Management Fault Tree Data Storage and Retrieval System, which track historic occurrence information and lessons learned specific to SRS facilities and operations.

Since the implementation of the Site Item Reportability and Issue Management (SIRIM) program in 1991, which assigns the responsibilities and requirements for reporting abnormal events and Accidents at SRS, more than 425 abnormal events involving waste management activities and operations have been documented (WSRC 1994b, c). These events were reviewed to determine whether (1) workers were physically injured, (2) radioactive or hazardous material was inadvertently released to the environment, or (3) the occurrence, if not resolved, could have caused significant consequences to workers, members of the public, or the environment. One event, involving a procedural violation of the nuclear criticality safety limits (maximum permissible plutonium inventory per waste container) established for the Solid Waste Disposal Facility, was considered to have the potential to have caused major impacts (an inadvertent criticality and potential worker fatality). The criticality limits were exceeded because the plutonium inventory placed in the waste containers was incorrectly calculated. As an immediate corrective action, DOE suspended all shipments of transuranic waste to the Solid Waste Disposal Facility from SRS facilities that generate transuranic waste. Before resuming shipments, DOE (1) ensured that no potential criticality hazards existed as a result of the limits being exceeded and (2) independently evaluated each facility that generates transuranic waste to ensure that the deficiencies had been resolved and that the facilities could correctly calculate the inventories of waste materials being sent to the Solid Waste Disposal Facility.

DOE also evaluated events that occurred prior to implementation of the Site Item Reportability and Issue Management System in 1991. The Waste Management Fault Tree Data Storage and Retrieval System data base documents several hundred events occurring between 1988 and 1991. Eight of the 13 events involving the management of liquid high-level radioactive wastes (such as is done at the F- and H­Area tank farms) involved worker doses in excess of established DOE limits; 2 involved liquid releases of radioactive material to Fourmile Branch; 1 involved an airborne release of radioactive particulates to the atmosphere; and 2 involved personnel assimilations of radioactive particulates.

Most of the abnormal events resulting from nontank farm operations were nonradiological in nature, such as minor physical injuries (e.g., cuts, falls), or involved minor leaks of radioactive material that did not result in airborne releases to the environment or a measurable dose to personnel. However, one event involved the flooding of a shallow land disposal unit as a result of heavy rains over a period of several days. This event, which occurred in August 1990, caused several metal boxes containing low-level radioactive waste to flood. In addition, when the trench flooded, several of the boxes floated, causing the stacking configuration of waste containers in the disposal unit to change. DOE assessments concluded that there were no releases of radioactive material to the environment.

Abnormal events from the beginning of Solid Waste Disposal Facility and the tank farm facilities operations in early 1953 through 1988 are discussed in the safety analysis reports for these facilities. At the tank farms, 17 occurrences were noted as significant: 9 liquid releases to Fourmile Branch, 6 personnel assimilations, and 2 airborne releases of radioactive particulates to the atmosphere. At the Solid Waste Disposal Facility, events primarily involved spills or leaks of organic solvents and small fires (limited to only one or a few waste containers) attributed to spontaneous chemical combustion resulting from improper packaging and did not result in measurable or significant releases of radioactive material. Since 1981, no fires have occurred in the transuranic waste storage drums, culverts, or carbon steel boxes at the Solid Waste Disposal Facility.


F.4 Accident Analysis Methodology


National Environmental Policy Act (NEPA) guidance issued by the DOE Office of NEPA Oversight (DOE 1993) recommends that accident impact analyses "...reference Safety Assessments and Safety Analysis Reports, if available." Most of the facilities considered in this eis have pre-existing safety documentation that analyzes the consequences and risks associated with operating the facilities. In accordance with this NEPA guidance, existing safety documentation was referred to during the preparation of the accident analysis portion of this eis. This appendix used three Westinghouse Savannah River Company technical reports (WSRC 1994c, d, and e) as the basis for the accident analysis information presented. These technical reports used safety analysis reports, preliminary safety analysis reports, hazard assessment documents, basis for interim operations documents, safety assessments, and other safety evaluations.

This analysis assessed the effects of radiological releases on four receptor groups in order to compare results among the alternatives. They are:

- uninvolved worker at 100 meters: an individual 100 meters (328 feet) from the point of a release

- uninvolved worker at 640 meters: an individual 640 meters (2,100 feet) from the point of a release

- offsite maximally exposed individual: a hypothetical member of the public who lives along the SRS boundary and who would receive the largest exposure from a release

- offsite population within 80 kilometers (50 miles): all the people within an 80-kilometer (50­mile) radius of SRS

AXAIR89Q (WSRC 1994f), a computer code developed specifically for analyzing the consequences of accidental releases of airborne radioactive particulates from SRS, was used to calculate the consequences to the receptor groups identified above for each of the accident scenarios postulated in this appendix. Consequences for the uninvolved workers and the offsite maximally exposed individual were calculated using 50 percentile meteorological assumptions (meaning that half the time meteorological conditions such as wind speed and barometric pressure are better than the assumption, and half the time they are worse), in accordance with DOE guidance (DOE 1993). DOE believes that the 50 percentile meteorological assumptions provide an estimate of the consequences under more realistic exposure conditions than would be expected if one of the postulated Accidents occurs. The AXAIR89Q computer code, which calculates population doses differently than doses for individuals, is not programmed to determine the population dose for meteorological conditions not exceeded 50 percent of the time. Therefore, for the offsite population within 80 kilometers (50 miles), DOE assumed very conservative meteorological conditions within 99.5 percentile. As a result, the consequences from postulated accidents are higher than would normally be expected for the offsite population.

As noted above, uninvolved workers are evaluated at 100 and 640 meters (328 and 2,100 feet). Typically, uninvolved workers at 100 meters (328 feet) are in a facility's emergency planning zone, which generally extends to the facility's boundary. However, uninvolved workers at 640 meters (2,100 feet) are likely to be outside a facilityís emergency planning zone, and it typically would take longer to notify these workers of an accident at the facility. The purpose of presenting accident impacts for the uninvolved workers at these two distances is to provide a comparison of results for uninvolved workers who are likely to be initially aware of an accident and those who are not. It should be noted that the methodology described in the following sections does not take credit for emergency responses to Accidents (e.g., evacuating personnel to a safe distance or notifying the public to take shelter) in determining potential effects on workers or members of the public. To minimize the potential for human exposures and impacts to the environment if an accident occurs, SRS has established an emergency plan (WSRC 1994d) that governs responses to accidents. Section F.8 summarizes the SRS Emergency Plan.

A maximum credible design basis earthquake at SRS, estimated to occur once every 5,000 years, could potentially impact multiple facilities within a single facility area, resulting in the release of radioactive and/or toxic materials. It is also possible, although probably less likely, that an earthquake of the same magnitude could damage facilities in more than one facility area (e.g., F- and H-Areas), resulting in simultaneous releases to the environment. See Section F.6.


F.4.1 RADIOLOGICAL ACCIDENT ANALYSIS METHODOLOGY


This appendix presents quantitative impacts to SRS workers and members of the public from postulated radiological Accidents using the following parameters: dose, accident frequency, latent fatal cancers, and risk of latent fatal cancers per year. These parameters were either referenced in or developed from information provided in the following technical reports: Bounding Accident Determination for the Accident Input Analysis of the SRS Waste Management Environmental Impact Statement (WSRC 1994e), Solid Waste Accident Analysis in Support of the Savannah River Waste Management Environmental Impact Statement (WSRC 1994c), and the Liquid Waste Accident Analysis in Support of the Savannah River Waste Management Environmental Impact Statement (WSRC 1994b). The quantities of radioactive materials and how these materials affect humans are important in determining health effects. The International Commission on Radiological Protection has made specific recommendations for quantifying these health effects. Results are presented in terms of latent fatal cancers calculated using the ICRP-60 conversion factors of 0.0005 latent fatal cancers per rem for the public and 0.0004 latent fatal cancers per rem for workers if the dose is less than 20 rem. For doses of 20 rem or more, the ICRP-60 conversion factors are doubled (ICRP 1991).

A quantitative analysis of these facilities is not possible because some of the facilities proposed for waste management activities are in the pre-design or conceptual stage of development. Therefore, a qualitative discussion of accident impacts is provided for proposed facilities for which a quantitative accident analysis does not exist.

Additionally, this analysis presents potential impacts to involved workers from postulated Accidents qualitatively rather than quantitatively for several reasons, the most relevant being that no adequate methodology exists for calculating meaningful consequences at or near the location where the accidental release occurs. The following example illustrates this concept.

A typical method for calculating the dose to an involved worker is to assume that the material is released in a room occupied by the individual and that the material instantly disperses throughout the room. Because the involved worker is assumed to be in the room when the release occurs, this worker probably would breathe some fraction of the radioactive (or hazardous) materials for some number of seconds before leaving the room. Typically, estimates of exposure time are based on assumptions made about worker response to the incident (e.g., how long before the worker leaves the room, or whether during evacuation the worker passes through an area of higher airborne concentration). The uncertainty of estimation is extremely great, and no additional insight into the activity is available because the occurrence is assumed to be undesirable; therefore, it is not necessary to perform the calculations. Historical evidence indicates that room contaminations are nonfatal Accidents with the potential for minor personnel contamination and assimilation.

DOE accepts that if the exposed individual is close enough to the location of the accident, it will be impossible to show acceptable dose consequences against typical guidelines. This is especially true if all Accidents with a frequency as low as once in a million years -- beyond which it is not possible to statistically demonstrate protection of worker life from standard hazards in the workplace -- must be considered. For example, it is more likely that an employee would be fatally injured by falling equipment during an earthquake severe enough to occur only once every 5,000 years than from the radiological dose that individual would receive from materials released during the earthquake. Therefore, this appendix addresses potential consequences to involved workers qualitatively. DOE assumes that the immediate impacts of the accident (in this case an earthquake) to the worker would be from the facility in which the worker was located at the time of the accident; while the consequences from another facility affected during the earthquake would have little immediate impact upon an "involved" worker.

Many accident scenarios can be postulated for each SRS facility; to attempt to analyze all potential accident scenarios and their impacts would not be useful or meaningful. However, a broad spectrum of Accidents can usually be identified and analyzed for a given facility to provide an understanding of the risks associated with performing activities in that facility. Safety analysis reports and other safety documentation usually analyze a broad spectrum of accidents that are considered credible (i.e., they are expected to occur at least once every one million years) and estimate their potential impacts on workers, the environment, and the public.

For this eis, the term "representative bounding accident" means postulated events or Accidents that have higher risks (i.e., consequences times frequencies) than other accidents postulated within the same frequency range. For example, the accident scenario within each frequency range (defined in Table F-1) that presents the highest risk (i.e., consequence times frequency) to the offsite maximally exposed individual is the representative bounding accident for that frequency range because its risk is higher than that of other accidents within the same frequency range. Determining the representative bounding accident is part of a "binning" process, whereby all the accident scenarios identified for a facility under a specific alternative would be assigned to a selected frequency range. The highest-risk accident scenario within each frequency range is then designated the representative bounding accident. It should be noted that the consequence value used to calculate risk is dose to the offsite maximally exposed individual.

Once the representative bounding Accidents are identified, it is not necessary to further consider other accident scenarios for that particular alternative. The bounding accident scenarios are further evaluated to provide accident impacts for the receptor groups. An evaluation of the risks associated with the representative bounding accidents for facilities associated with a given alternative can establish an understanding of the overall risk to workers, members of the public, and the environment from operating facilities under a specific alternative. However, since some accident impacts are not represented in quantitative terms, the term "representative" must preface the phrase "bounding accident." This is because without a complete list of quantitative impacts from accidents for all facilities (existing and proposed), the true bounding accidents may not be absolutely defined. Figure F-1 shows the concept of bounding risk Accidents . Section F.5 identifies the representative bounding accidents postulated for the facilities considered in this eis.

Figure F-1.


F.4.2 CHEMICAL HAZARDS ANALYSIS METHODOLOGY


To fully understand the hazards associated with SRS facilities associated with the alternatives considered in this eis, it is necessary to analyze potential Accidents involving hazardous as well as radiological materials. Because the long-term health consequences of human exposure to hazardous materials are not as well understood as those related to radiation exposure, a determination of potential health effects from exposures to hazardous materials is more subjective than a determination of health effects from exposure to radiation. Therefore, the consequences of accidents involving hazardous materials postulated in this appendix are presented in terms of airborne concentrations at various distances from the accident. The quantities and airborne concentrations at various receptor locations were extracted from technical reports (WSRC 1994b, c) supporting this eis.

Because safety documentation exists for many of the facilities within the scope of this eis, it was used whenever possible to determine potential events involving hazardous materials and the health effects that could result from inadvertent releases of these materials to the environment. However, because these safety documents were developed for different purposes, the methodologies used to analyze potential events at the facilities are sometimes different. In general, the methodology used to develop most of the existing safety documentation included: (1) identifying hazardous materials present in quantities greater than reportable quantities (40 CFR 302.4), threshold planning quantities (40 CFR 355), or threshold quantities (40 CFR 29:1910.1000, Subpart Z); (2) modeling an unmitigated release of those hazardous materials to the atmosphere to determine airborne concentrations at the various receptor locations [100 meters (328 feet), 640 meters (2,100 feet), and the nearest SRS boundary]; and (3) comparing those airborne concentrations to Emergency Response Planning Guideline (ERPG) values established by the American Industrial Hygiene Association (AIHA 1991).

Three ERPG values (ERPG-1, -2, or -3) are typically assigned to hazardous materials or chemicals in terms of airborne concentration (milligrams per cubic meter or parts per billion). The types of emergency response actions required to minimize worker and public exposure are determined by considering which of the three ERPG values is exceeded. The three types of ERPG values defined are:

- ERPG-1: The maximum airborne concentration below which it is believed that nearly all individuals could be exposed for up to 1 hour without experiencing other than mild transient adverse health effects or perceiving a clearly defined objectionable odor.

- ERPG-2: The maximum airborne concentration below which it is believed that nearly all individuals could be exposed for up to 1 hour without experiencing or developing irreversible or other serious health effects or symptoms that could impair their abilities to take protective action.

- ERPG-3: The maximum airborne concentration below which it is believed nearly all individuals could be exposed for up to 1 hour without experiencing or developing life-threatening health effects.

The American Industrial Hygiene Association has not established ERPG values for some hazardous materials. When such materials would be present at SRS facilities in substantial quantities (exceeding the various threshold criteria), airborne concentrations of these materials at the various receptor locations were compared to the most restrictive exposure limits established by other recognized organizations to control worker exposures to hazardous materials. Table F-3 lists the hierarchy of exposure limits that DOE used in place of ERPG values to determine potential health effects resulting from the postulated hazardous material releases.

For facilities for which safety documentation was not developed in accordance with the methodology described above, the typical difference in the methodology involved which hazardous materials were required to be evaluated, not how the evaluations were performed. In the case of the Defense Waste Processing Facility's Organic Waste Storage Tank, for example, which was recently evaluated in the Final Supplemental Environmental Impact Statement, Defense Waste Processing Facility (DOE 1994b), hazardous materials designated "Extremely Hazardous Substances" in accordance with the Emergency Planning and Community Right-to-Know Act of 1986 were evaluated, rather than materials that exceed the reportable, threshold, or threshold planning quantities.

The potential events at the various facilities analyzed in this eis that could release hazardous materials to the environment were evaluated using one of the methodologies described above. DOE further analyzes potential events involving hazardous materials at the Consolidated Incineration Facility and

E-, B-, and N-Areas (WSRC 1994c). DOE further discusses the analysis methodology for events involving hazardous materials at the F/H-Area Effluent Treatment Facility, the F/H-Area tank farms, the Defense Waste Processing Facility's Organic Waste Storage Tank, and waste storage tanks at the Savannah River Technology Center (WSRC 1994b).

Although safety documentation exists for most of the facilities and facility areas that perform waste management activities, there is no safety documentation that analyzes potential events involving hazardous materials in M-Area. Using the second methodology described above, it was determined that sulfuric acid would be the only chemical present in M-Area in sufficient quantities to warrant further evaluation in this eis. Consistent with the methodologies, DOE analyzed an unmitigated release of the entire sulfuric acid inventory in M-Area using a commercially available computer code called EPICode (Homann 1988) that models the atmospheric dispersion of chemicals released to the environment. DOE then compared the resulting airborne concentrations against the ERPG values for sulfuric acid to determine the potential health effects.


Table F-3. Hierarchy of established limits and guidelines used to determine impacts from postulated hazardous material Accidents


Primary airborne concentration guideline


Hierarchy of alternative guidelines
(if primary guidelines are unavailable)


Reference of
alternative guideline
ERPG-3
EEGLb (30-minute exposure)
IDLHc
NAS (1985)
NIOSH (1990)
ERPG-2
EEGL (60-minute exposure)
LOCd
PEL-Ce
TLV-Cf
TLV-TWA
g multiplied by 5
NAS (1985)
EPA (1987)
CFR (1990)
ACGIH (1992)
ACGIH (1992)
ERPG-1
TWA-STELh
TLV-STELi
TLV-TWA multiplied by 3
CFR (1990)
ACGIH (1992)
ACGIH (1992)

a. This table is based on information presented in the Toxic Chemical Hazard Classification and Risk Acceptance Guidelines for Use in DOE Facilities (WSRC 1992).

b. Emergency Exposure Guidance Level (EEGL): "A concentration of a substance in air (as a gas, vapor, or aerosol) that may be judged by the Department of Defense to be acceptable for the performance of specific tasks during emergency conditions lasting for a period of 1 to 24 hours. Exposure at an EEGL might produce reversible effects that do not impair judgment and do not interfere with proper responses to an emergency." The EEGL is "...a ceiling guidance level for a single emergency exposure, usually lasting from 1 to 24 hours -- an occurrence expected to be infrequent in the lifetime of a person."

c. Immediately Dangerous to Life and Health (IDLH): "The maximum concentration from which, in the event of respirator failure, one could escape within 30 minutes without a respirator and without experiencing any escape-impairing (e.g., severe eye irritation) or irreversible health effects."

d. Level of Concern (LOC): "The concentration of an extremely hazardous substance in air above which there may be serious irreversible health effects or death as a result of a single exposure for a relatively short period of time."

e. Permissible Exposure Limit - Ceiling (PEL-C): "The employeeís exposure which shall not be exceeded during any part of the work day."

f. Threshold Limit Value - Ceiling (TLV-C): "The concentration that should not be exceeded during any part of the working exposure."

g. Threshold Limit Value - Time Weighted Average (TLV-TWA): "The time-weighted average concentration for a normal 8-hour workday and a 40-hour workweek, to which nearly all workers may be repeatedly exposed, day after day, without adverse effect."

h. Time Weighted Average - Short-Term Exposure Limit (TWA-STEL): "The employeeís 15­minute time weighted average exposure which shall not be exceeded at any time during a work day unless another time limit is specified...."

i. Threshold Limit Value - Short-Term Exposure Limit (TLV-STEL): "The concentration to which workers can be exposed continuously for a short period of time without suffering from (1) irritation, (2) chronic or irreversible tissue damage, or (3) narcosis of sufficient degree to increase the likelihood of accidental injury, impair self-rescue, or materially reduce work efficiency, and provided that the daily TLV-TWA is not exceeded."



F.5 Accident Analysis by Waste Type


This section presents potential impacts from postulated radiological and chemical Accidents at the facilities that are or could be involved in the management of waste materials at SRS. This section has been organized according to waste type, with an analysis for each of the alternatives presented in this eis. Each of the following sections includes a list of the facilities, postulated radiological accident impacts, and postulated chemical accident impacts associated with the waste type.


F.5.1 HIGH-LEVEL WASTE


The following sections address the impacts of postulated Accidents associated with the alternatives considered in this eis for the management of liquid high-level waste.


F.5.1.1 Facilities and Accidents: High-Level Waste

The accident analyses considered all facilities and processes involved in the management of liquid high­level waste. The facilities were identified from the information on high-level waste provided in Chapter 2 of this eis. The facilities involved in the management of high-level waste for all alternatives considered in this eis are the F/H-Area Evaporators, the Replacement High-Level Waste Evaporator, the New Waste Transfer Facility, the F/H-Area tank farms, and the F/H-Area Effluent Treatment Facility. Descriptions of these facilities are provided in Appendix B. For each of these facilities, a list of postulated accident scenarios was developed to support high-level waste accident analyses for each alternative.

Table F-4 lists potential Accidents associated with the management of high-level waste. These accidents were extracted from the technical reports supporting this eis (WSRC 1994b, c, and e).


Table F-4. List of potential Accidents associated with the management of high-level waste.



No.


Accident description
Annual freq.
Dosea
(rem)
RiskRisk (rem/yr)
1
RHLWEb release due to a feed line break
7.00E-02
2.73E-03
1.91E-04
2
H-Area airborne release due to waste tank filter fire
2.50E-02
3.68E-03
9.20E-05
3
RHLWEb release due to design basis earthquake
2.00E-04
8.16E-02
1.63E-05
4
F-Area airborne release due to waste tank filter fire
2.50E-02
6.39E-04
1.60E-05
5
RHLWEb release due to evaporator pressurization and breach
5.09E-05
2.03E-01
1.04E-05
6
RHLWEb release due to hydrogen explosion
1.71E-04
4.58E-02
7.83E-06
7
H-Area airborne release due to organic fire - waste tank
5.00E-03
1.35E-03
6.75E-06
8
RHLWEb release due to HEPAc filter fire
1.00E-02
4.55E-04
4.55E-06
9
H-Area airborne release due to hydrogen fire - waste tank
5.00E-03
7.37E-04
3.69E-06
10
F-Area liquid release due to waste tank overflow
9.00E-02
2.37E-05
2.13E-06
11
H-Area liquid release due to waste tank overflow
9.00E-02
2.00E-05
1.80E-06
12
F-Area airborne release due to organic fire - waste tank
5.00E-03
2.34E-04
1.17E-06
13
H-Area liquid release due to earthquake
2.00E-04
3.41E-03
6.82E-07
14
F-Area airborne release due to hydrogen fire - waste tank
5.00E-03
1.28E-04
6.40E-07
15
H-Area airborne release due to hydrogen explosion - pump tank
2.00E-05
1.13E-02
2.26E-07
16
F-Area airborne release due to hydrogen explosion - pump tank
2.00E-05
7.80E-03
1.56E-07
17
H-Area airborne release due to waste tank overpressurization
1.00E-01
9.80E-07
9.80E-08
18
RHLWEb release due to design basis tornado
4.00E-05
6.20E-04
2.50E-08
19
Normal processing with tritiumtritium ETFd airborne release due to straight wind
1.20E-03
1.47E-05
1.76E-08
20
Normal processing other than tritiumtritium ETFd airborne release due to straight wind
1.20E-03
1.46E-05
1.75E-08
21
F-Area airborne release due to waste tank overpressurization
1.00E-01
1.70E-07
1.70E-08
22
Normal processing with tritiumtritium ETFd liquid release due to straight wind
1.20E-03
9.40E-06
1.13E-08
23
F-Area liquid release due to hydrogen explosion - pump tank
2.00E-05
5.47E-04
1.09E-08
24
Normal processing other than tritiumtritium ETFd liquid release due to straight wind
1.20E-03
7.70E-06
9.24E-09
25
Normal processing with tritiumtritium ETFd airborne release due to tornado
4.50E-05
2.04E-04
9.18E-09
26
Normal processing other than tritiumtritium ETFd airborne release due to tornado
4.50E-05
2.03E-04
9.14E-09
27
F-Area liquid release due to earthquake
2.00E-04
3.38E-05
6.76E-09
28
Normal processing with tritiumtritium ETFd airborne release due to earthquake
2.00E-04
2.77E-05
5.54E-09
29
H-Area liquid release due to hydrogen explosion - pump tank
2.00E-05
2.57E-04
5.14E-09
30
H-Area liquid release due to vehicle crash (scenario A; see #63)
3.50E-05
1.36E-04
4.76E-09
31
H-Area waste release from feed pump riser
1.90E-04
1.87E-05
3.55E-09
32
F-Area waste release from feed pump riser
1.90E-04
1.10E-05
2.09E-09
33
Normal processing with tritiumtritium ETFd liquid release due to earthquake
2.00E-04
9.40E-06
1.88E-09
34
Normal processing other than tritiumtritium ETFd liquid release due to earthquake
2.00E-04
7.70E-06
1.54E-09
35
H-Area airborne release due to hydrogen explosion - evaporator
5.00E-06
2.93E-04
1.47E-09
36
H-Area airborne release due to hydrogen explosion - CTSe tank
5.00E-06
2.93E-04
1.47E-09
37
H-Area liquid release due to waste tank overpressurization
1.00E-01
9.34E-09
9.34E-10
38
F-Area liquid release due to waste tank overpressurization
1.00E-01
5.52E-09
5.52E-10
39
H-Area liquid release due to tank leak
3.00E-02
1.76E-08
5.28E-10
40
Normal processing other than tritiumtritium ETFd airborne release due to earthquake
2.00E-04
2.50E-06
5.00E-10
41
Design basis ETFd liquid release due to straight wind
9.84E-06
4.70E-05
4.62E-10

Table F-4. (continued).



No.


Accident description
Annual freq.
Dosea
(rem)
RiskRisk (rem/yr)
42
Normal processing with tritiumtritium ETFd liquid release due to tornado
4.50E-05
9.40E-06
4.23E-10
43
Normal processing other than tritiumtritium ETFd liquid release due to tornado
4.50E-05
7.70E-06
3.47E-10
44
H-Area airborne release due to tornado
3.00E-05
9.90E-06
2.97E-10
45
F-Area liquid release due to tank leak
3.00E-02
8.82E-09
2.65E-10
46
F-Area airborne release due to tornado
3.50E-05
6.00E-06
2.10E-10
47
F-Area airborne release due to hydrogen explosion - evaporator
5.00E-06
3.25E-05
1.63E-10
48
F-Area airborne release due to hydrogen explosion - CTSe tank
5.00E-06
3.25E-05
1.63E-10
49
F-Area liquid release due to hydrogen explosion - CTSe tank
5.00E-06
3.04E-05
1.52E-10
50
H-Area liquid release due to hydrogen explosion - CTSe tank
5.00E-06
2.57E-05
1.29E-10
51
F-Area liquid release due to hydrogen explosion - evaporator
5.00E-06
2.37E-05
1.19E-10
52
Design basis ETFd airborne release due to straight wind
9.84E-06
1.12E-05
1.10E-10
53
Design basis ETFd airborne release due to tornado
3.69E-07
2.83E-04
1.04E-10
54
H-Area liquid release due to a hydrogen explosion - evaporator
5.00E-06
2.00E-05
1.00E-10
55
Normal processing with tritiumtritium ETFd airborne release due to transfer error
1.80E-02
4.46E-09
8.03E-11
56
Design basis ETFd liquid release due to earthquake
1.64E-06
4.70E-05
7.71E-11
57
Normal processing with tritiumtritium ETFd airborne release due to corrosion damage
8.80E-02
8.75E-10
7.70E-11
58
F-Area liquid release during catherization
7.00E-02
6.76E-10
4.73E-11
59
H-Area liquid release during catherization
7.00E-02
5.70E-10
3.99E-11
60
Normal processing other than tritiumtritium ETFd airborne release due to transfer error
1.80E-02
1.72E-09
3.10E-11
61
Normal processing other than tritiumtritium ETFd airborne release due to corrosion damage
8.80E-02
3.38E-10
2.97E-11
62
Design basis ETFd airborne release due to leaks
2.13E-02
1.35E-09
2.88E-11
63
H-Area liquid release due to a vehicle crash (scenario B; see #30)
3.50E-05
7.10E-07
2.49E-11
64
Design basis ETFd airborne release due to overflow
1.48E-03
1.44E-08
2.13E-11
65
Design basis ETFd liquid release due to tornado
3.69E-07
4.70E-05
1.73E-11
66
Design basis ETFd airborne release due to earthquake
1.64E-06
8.40E-06
1.38E-11
67
Normal processing with tritiumtritium ETFd airborne release due to a siphoning incident
2.60E-03
1.12E-09
2.91E-12
68
Design basis ETFd airborne release due to spill
1.48E-03
1.88E-09
2.78E-12
69
Normal processing other than tritiumtritium ETFd airborne release due to siphoning incident
2.60E-03
4.34E-10
1.13E-12
70
Design basis ETFd airborne release due to transfer error
1.48E-04
6.86E-09
1.02E-12
71
Design basis ETFd airborne release due to corrosion damage
7.22E-04
1.35E-09
9.75E-13
72
Design basis ETFd airborne release due to a siphoning incident
2.13E-05
1.73E-09
3.68E-14

a. The dose given is for the offsite maximally exposed individual using 99.5 percentile meteorology.

b Replacement High-Level Waste Evaporator.

c. High efficiency particulate air.

d. Effluent Treatment Facility.

e. Concentrate transfer system.



F.5.1.2 Accident Analysis for the High-Level Waste No-Action Alternative

This section addresses the effects of postulated Accidents associated with the no-action alternative considered for high-level waste.

Impacts from Postulated Radiological AccidentsAccidents

DOE identified the representative bounding accident scenarios for the no-action alternative from the list of potential radiological Accidents presented in Table F-4. Figure F-2 identifies the highest-risk accident scenarios in each frequency range. As shown in Figure F-2, for all but the lowest frequency range, the representative bounding accidents are associated with the operation of the Replacement High-Level Waste Evaporator. Table F-5 lists the high-level waste representative bounding accidents, accident consequences, and latent fatal cancers for exposed workers and the public.

Accident Scenario 1 -Replacement High-Level Waste Evaporator release due to a feed line break: A break in the feed line to the Replacement High-Level Waste Evaporator could occur if feed was pumped after the feed line became plugged. The feed line can become plugged due to excess sludge and suspended solids collecting and solidifying in stagnation points within the feed line. If feed pumping continued, the excess pressure would eventually cause a rupture in the feed line or jumper connection. Numerous indicators would alert the operator of a feed line rupture. In the event of a break, the automatic level control system in the evaporator would indicate decreased lift activity as the level of liquid in the evaporator dropped. Because supernatant would now be accumulating in the evaporator cell, the evaporator sump and differential pressure sensors in the ventilation system would also indicate leakage. Finally, the radiation monitor in the stack would register an increase in the radiation level of material leaving the ventilation system.

The Replacement High-Level Waste Evaporator is planned to operate from 1999 to 2018, when DOE expects to have completed high-level waste management activities. Between 1994 and 1999 -- before the Replacement High-Level Waste Evaporator is operational -- the highest-risk accident in the anticipated accident range would be Accident Scenario 2: H-Area airborne release due to waste tank filter fire.

Accident Scenario 3 -Replacement High-Level Waste Evaporator release due to a design basis earthquake: Studies reported in the supporting technical report (WSRC 1994c) indicate that SRS is located in an area where moderate damage could occur from earthquakes. In this accident scenario, an earthquake is assumed to disrupt the operation of the evaporator facility. The feed input and bottoms output are assumed not to be affected during the earthquake, and the steam supply is assumed to continue to flow at the normal rate; therefore, the evaporator contents continue to be boiled off as normal. However, the demister is assumed to be damaged and its performance is degraded. The accident results in a release to the environment through a broken process line between the evaporator vessel demister and condenser. The highest-risk accident in this frequency range between 1994 and 1999 would be Accident Scenario 7: H-Area airborne release due to waste tank organic fire.

Figure F-2.

Accident Scenario 5 -Replacement High-Level Waste Evaporator release due to evaporator pressurization and breach: An evaporator breach would be possible if the internal pressure in the evaporator exceeded the design pressure, which could be caused by demister mesh pad blockage; excessive levels of condensate and vent line blockage; or steam bundle failures. A breach of the evaporator would result in an energetic release of the vessel contents into the evaporator cell and a subsequent unfiltered airborne release of waste into the atmosphere when the high efficiency particulate air filters become overloaded. The associated pressure increase would be detected by independent bubble tube pressure sensors within the evaporator vessel. These sensors are tied to interlocks that would provide for mitigation of the event. These devices must fail for an overpressurization to occur. From 1994 to 1999 -- before the Replacement High-Level Waste Evaporator is operational -- the highest-risk accident in this frequency range would be Accident Scenario 15: H-Area airborne release due to pump tank hydrogen explosion.

Accident Scenario 53 -Design basis F/H-Area Effluent Treatment Facility airborne release due to a tornado: Damage to equipment that would result in a release of radioactivity could occur during a sustained wind or tornado. The F/H-Area Effluent Treatment Facility is designed for a sustained wind speed of 137 kilometers (85 miles) per hour. Outside tanks and piping would be subjected to the full force of the wind and could be struck by windblown objects, either of which could result in a release of radioactivity. Equipment and piping located inside a process building could be damaged by roof debris and falling portions of the upper structure. Some of the liquid released would evaporate and become airborne and some would drain to surface water streams. No credit is taken for tank dikes, high efficiency particulate air filtration, or for a release from an elevated stack.


F.5.1.3 Accident Analysis for the High-Level Waste for Minimum, Expected, and Maximum Waste Forecasts

This section addresses the impacts of postulated Accidents associated with alternatives A, B, and C considered for high-level waste. The facilities that support alternative A, alternative B, and alternative C and their periods of operation are identical to the facilities and periods of operation that support the
no-action alternative. Thus, postulated radiological accident scenarios and their impacts are the same as described in Section F.5.1.2.

DOE assumes that conclusions for representative bounding accident scenarios for high-level waste management under the alternatives would not be changed by the minimum, maximum, and expected waste forecasts. Since the accident analysis for each accident scenario is based on a conservative assumption of peak utilization of the facility, differences between minimum, maximum, and expected waste forecast would only affect how long the facility would operate. Therefore, while consequence or frequency for postulated Accidents are not changed, the expected duration of risk from a facility-specific accident scenario could be longer or shorter, as appropriate. Impacts for these cases are addressed in the representative bounding accident descriptions.


F.5.1.4 Impacts to Involved Workers from Accidents Involving High-Level Waste

The highest risk accident scenarios for high-level waste involve releases from the Replacement High­Level Waste Evaporator, tank farm tanks, or the F/H-Area Effluent Treatment Facility. These releases would be due to feed line breaks, overpressurizations and breaches, explosions, or natural disasters. Of these accident scenarios and their postulated releases, the ones associated with the Replacement High­Level Waste Evaporator are assumed to have the greatest potential for adverse effects on involved workers. This assumption is based on the higher consequences for the Replacement High­Level Waste Evaporator accident scenarios than those for the tank farm or F/H­Area Effluent Treatment Facility. While some exposure to involved workers could occur due to an accidental release, timely evacuation as the result of monitoring activities would prevent substantial radiological exposure. DOE assumes no fatalities would be likely from radiological consequences.


F.5.1.5 Impacts from High-Level Waste Chemical Accidents

The results of the chemical hazards assessment completed for chemicals stored or processed in facilities located in the area of the F/H-Area tank farms as addressed in the Final Supplemental Environmental Impact Statement, Defense Waste Processing Facility are presented in Table F-6. The calculated 100­meter (328­foot), 640­meter (2,100-foot), and offsite chemical concentrations are compared to the appropriate ERPG-1, -2, and -3 guideline concentrations. A nitric acid release from Building 241­61H is the only accident with calculated concentrations that exceed the ERPG-3 limit at 100 and 640 meters (328 and 2,100 feet).

Because the concentrations calculated for the SRS boundary for every chemical do not exceed the respective ERPG-1 concentrations (even assuming a total unmitigated release of all chemicals), specific accident scenarios (i.e., an accident initiator and resulting accident progression resulting in a release to the environment) were not developed, nor were corresponding frequencies of occurrence identified. More realistic accident scenarios and associated frequencies were not necessary because the bounding consequences for the unmitigated release of the entire inventory, however improbable, were within established guidelines.

The nitric acid concentrations that exceed the ERPG-3 limit could pose a risk of major reversible tissue damage. Because the chemical concentration in air decreases with distance from the release location, offsite individuals would be exposed to chemical concentrations less than the ERPG-1 limit. However, onsite personnel in the immediate area of a release could encounter concentrations that exceed the ERGP-3 limit. While perhaps not instantly lethal, even short exposures could be extremely dangerous.

The F/H-Area Effluent Treatment Facility is classified as a low-hazard facility based on the chemical hazards assessment contained in the Effluent Treatment Facility Hazards Assessment Document (WSRC 1993). Table F-7 lists the results of this chemical assessment. The calculated 100-meter (328-foot), 640-meter (2,100-foot), and offsite chemical concentrations are compared to the appropriate ERPG-1, -2, and -3 guideline concentrations. A nitrogen dioxide release from the storage area and a nitric acid release from process chemical storage tanks are the only postulated Accidents with calculated concentrations that exceed the ERPG-3 limit at 100-meters (328-feet). However, no accidents resulted in air concentrations at 640-meters (2,100-feet) or the SRS boundary that exceeded ERPG-3 guidelines. Additionally, the nitrogen dioxide release scenario had a calculated concentration at the SRS boundary that exceeded the ERPG-1 guideline but remained under the ERPG-2 guideline.

No chemical hazards analysis or accident consequence analysis exist for the chemicals at the Replacement High-Level Waste Evaporator. However, it is assumed that the chemical hazards posed by this facility would be bounded by those posed by existing evaporators in the F/H­Area tank farms.


F.5.2 LOW-LEVEL WASTE


This section evaluates the impacts of postulated Accidents associated with the alternatives considered in this eis for the management of low-level waste.


F.5.2.1 Facilities and Accidents: Low-Level Waste

The accident analyses considered all facilities and processes involved in the management of low-level waste. The facilities were identified from the low-level waste information provided in Chapter 2 of this eis. Table F-8 lists the facilities associated with each of the alternatives. Descriptions of these facilities are provided in Appendix B. For each facility, a list of postulated accident scenarios was developed to support the low-level waste accident analysis for each alternative.

Table F-9 lists potential Accidents associated with the management of low-level waste. This list was extracted from the technical reports supporting this eis (WSRC 1994b, c, d, and e). All the accidents listed in Table F-9 are supported by quantitative analyses. It should be noted that because accident impacts for proposed facilities are mainly qualitative, they are not listed in the table.



Table F-5. Representative bounding radiological accidents under the no-action alternative.


Point estimate of increased risk per yeara
(increased risk of fatal cancers per occurrence)b
Accident consequences
Latent fatal cancers







No.







Accident description




Frequency per year

(accident range)




Uninvolved worker at 100 meters
(rem)




Uninvolved worker at 640 meters
(rem)
Offsite maximally exposed individual (rem)




Population within 80 kilometersc
(person-rem)





Uninvolved worker at 100 meters





Uninvolved worker at 640 meters




Offsite maximally exposed individual





Population within 80 kilometers
1RHLWEd release due to a feed line break

7.00E-02e

(anticipated)
6.41E-012.28E-02 3.76E-041.81E+01 1.79E-05
(2.56E-04)
6.38E-07
(9.12E-06)
1.32E-08
(1.88E-07)
6.34E-04
(9.05E-03)
3RHLWEd release due to a design basis earthquake
2.00E-04

(unlikely)
1.92E+016.83E-01 1.12E-025.43E+02 1.54E-06
(7.68E-03)
5.46E-08
(2.73E-04)
1.12E-09

(5.60E-06)

5.43E-05

(2.72E-01)

5RHLWEd release due to evaporator pressurization and breach 5.09E-05

(extremely unlikely)
4.79E+011.70E+00 2.80E-021.35E+03 1.95E-06
(3.83E-02)
3.46E-08
(6.80E-04)
7.13E-10

(1.40E-05)

3.44E-05

(6.75E-01)

53Design basis ETFe airborne release due to tornado 3.69E-07

(beyond-extremely-unlikely)
2.17E-036.91E-05 3.90E-053.44E-04 3.20E-13

(8.68E-07)

1.02E-14

(2.76E-08)

7.20E-15

(1.95E-08)

6.35E-14

(1.72E-07)

a. Point estimate of increased risk per year is calculated by multiplying the consequence (dose) ¥ latent cancer conversion factor ¥ annual frequency.

b. Increased risk of fatal cancers per occurrence is calculated by multiplying the consequence (dose) ¥ latent cancer conversion factor.

c. A conservative assumption of 99.5 percentile meteorology was assumed for determining accident consequences for the exposed population within 80 kilometers. A less conservative meteorology (50 percentile) was used to determine the accident consequences for exposed individuals.

d. Replacement High-Level Waste Evaporator.

e. Effluent Treatment Facility.



Table F-6. Chemical hazards analysis results for the F/H-Area tank farm facilities.








Chemical






Release location





Quantity (kg)a
100-meter (328­foot) concentration (mg/m3)b
640-meter (2,100­foot) concentration (mg/m3)b




Offsite concentration (mg/m3)b





ERPG-1c (mg/m3)b





ERPG-2 (mg/m3)b





ERPG-3 (mg/m3)b
Nitric acidBldg. 241-61H 42,620.908.30E+021.00E+02 2.00E+005.20E+003.9E+01 7.70E+01
Phosphorous pentoxideBldg. 241-84H 0.457.50E-022.90E-02 3.10E-045.00E+002.50E+01 1.00E+02
AmmoniaBldg. 242-24H 13.64.50E-031.80E-03 2.40E-051.70E+011.40E+02 7.00E+02
Hydrochloric acidBldg. 280-1H 22.77.60E-033.00E-03 3.90E-054.50E+003.00E+01 1.50E+02
Sulfuric acidBldg. 280-1F 3,828.803.70E-062.20E-07 3.20E-092.00E+001.00E+01 3.00E+01

a. Kilograms. To convert to pounds multiply by 2.2046.

b. Milligrams per cubic meters of air.

c. Emergency Response Planning Guideline. See Table F-3.



Table F-7. F/H-Area Effluent Treatment Facility chemical hazards analysis results.









Segment description







Chemical







Quantity (kg)a
Onsite concentration 100 meters
(328 feet)
(mg/m3)b
Onsite concentration 640 meters
(2,100 feet) (mg/m3)b





Offsite concentration (mg/m3)b






ERPG-1c (mg/m3)b






ERPG-2c (mg/m3)b






ERPG-3c (mg/m3)b
Waste water collection tanks Lead4.41E-01 1.07E-024.24E-04 2.15E-051.50E-01 2.50E-017.00E+02
Waste water collection tanks Ammonia5.51E+01 1.34E+005.31E-02 2.68E-031.74E+01 1.39E+026.95E+02
Treatment building chemicals Ammonia5.85E+01 1.42E+005.36E-02 2.85E-031.74E+01 1.39E+026.95E+02
Treatment building chemicals Lead3.39E-01 8.24E-033.27E-04 1.65E-051.50E-01 2.50E-017.00E+02
Treatment building chemicals Mercury5.79E+00 1.41E-015.59E-03 2.82E-041.50E-01 2.00E-012.80E+01
Outside tanks and HEPAd filters Mercury3.09E+00 7.53E-012.99E-02 1.50E-031.50E-01 2.00E-012.80E+01
Storage areaNitrogen dioxide 3.30E+017.96E+01 3.16E+001.59E-01 8.00E-021.88E+00 5.64E+01
Storage areaSodium hydroxide 3.02E+027.34E-02 2.91E-031.47E-04 2.00E+004.00E+01 1.00E+02
Storage areaNitric acid 2.12E+025.17E+00 2.05E-011.03E-02 5.15E+003.87E+01 7.73E+01
Storage areaOxalic acid 1.13E+042.76E+02 1.09E+015.52E-01 2.00E+005.00E+00 5.00E+02
Process chemical storage tanks Sodium hydroxide2.81E+03 6.83E-012.71E-02 1.37E-032.00E+00 4.00E+011.00E+02
Process chemical storage tanks Nitric acid7.41E+03 1.81E+027.18E-00 3.61E-015.15E+00 3.87E+017.73E+01
Acid and caustic tanks Nitric acid
(e)
5.87E+002.33E-01 1.17E-025.15E+00 3.87E+017.73E+01
Acid and caustic tanks Sodium hydroxide4.01E+00 9.90E+003.93E-01 1.98E-022.00E+00 4.00E+011.00E+02

a. Kilograms. To convert to pounds multiply by 2.2046.

b. Milligrams per cubic meters of air.

c. Emergency Response Planning Guideline. See Table F-3.

d. High efficiency particulate air.

e. Quantity not available but is assumed to be bounded by the quantity for nitric acid in the Process Chemical Storage Tanks based upon comparison of airborne concentrations at 100 meters (328 feet).



Table F-8. Low-level waste facilities identified by alternative.




List of facilities



No action
Alternative A (limited treatment configuration)
Alternative C (extensive treatment configuration)
Alternative B
(moderate treatment configuration)
E-Area vaultsa
X
X
X
X
Reactor compactor
X
X
Xb
Xb
253-H compactor
X
X
Xb
Xb
M-Area compactor
X
X
Xb
Xb
Soil sort facilityc    
X
Non-alpha vitrification facilityc   

X
 
Consolidated Incineration Facility   

X


X
Offsite smelter   
X
X
Shallow land disposald
X
X
X
X

a. E-Area vaults includes low-activity waste vaults, intermediate-level tritium vaults, intermediate-level nontritium vaults; long-lived waste storage buildings.

b. These facilities are assumed to remain in operation until proposed facilities come on line.

c. Proposed facility.

d. Shallow land disposal includes the engineered low-level trenches, greater confinement disposal (boreholes and engineered trenches), and naval reactor hardware storage.



Table F-9. List of potential Accidents associated with the management of low-level waste.




No.


Accident description
Annual
frequency
Dosea
(rem)
RiskRisk (rem/yr)
1
Container breach at the eaV/ILNTVb
2.00E-02
2.60E-01
5.20E-03
2
Fire at the eaV/LLWSBc
8.30E-02
4.70E-02
3.90E-03
3
Fire at the eaV/LAWVd
8.30E-02
2.10E-02
1.74E-03
4
Fire at the eaV/ILTVe
8.30E-02
1.90E-02
1.58E-03
5
Container breach at the eaV/LAWVd
2.00E-02
4.00E-02
8.00E-04
6
Container breach at the eaV/ILTVe (scenario A; see #8)
2.00E-02
3.60E-02
7.20E-04
7
Fire at the eaV/ILNTVb
8.30E-02
8.60E-03
7.14E-04
8
Container breach at the eaV/ILTVe (scenario B; see #6)
2.00E-02
3.10E-02
6.20E-04
9
Container breach at the eaV/LLWSBc
2.00E-02
3.10E-02
6.20E-04
10
Explosion at CIFg - tank farm sump and diked area
1.90E-07
6.85E-03
1.30E-04
11
Fire at the ELLTf
8.30E-02
5.35E-05
4.44E-06
12
Large fire at CIFg
2.34E-04
1.07E-02
2.50E-06
13
High wind at the eaV/ILNTVb
1.00E-03
3.04E-04
3.04E-07
14
Earthquake at CIFg
1.00E-03
2.65E-04
2.65E-07
15
Tornado at the eaV/ILNTVb
2.00E-05
1.18E-02
2.36E-07
16
Explosion at CIFg - Rotary Kiln
1.50E-04
1.57E-03
2.36E-07
17
High velocity straight winds at CIFg
2.00E-02
5.23E-06
1.05E-07
18
Tornado at the eaV/LAWVd
2.00E-05
4.90E-03
9.80E-08
19
Tornado at the eaV/ILTVe
2.00E-05
4.40E-03
8.80E-08
20
Unintentional exhumation of ELLTf
8.30E-02
3.90E-07
3.24E-08
21
Explosion at CIFg - backhoe housing
4.00E-04
5.64E-05
2.26E-08
22
High wind at the eaV/ILTVe
1.00E-03
2.00E-05
2.00E-08
23
High wind at the eaV/LAWVd
1.00E-03
1.50E-05
1.50E-08
24
Explosion at CIFg - tank farm tank
3.40E-07
5.36E-03
1.82E-09

a. The dose given is for the offsite maximally exposed individual (MEI) using 99.5 percentile meteorology.

b. E-Area Vaults/Intermediate-Level Nontritium Vault.

c. E-Area Vaults/Long-Lived Waste Storage Buildings.

d. E-Area Vaults/Low-Activity Waste Vault.

e. E-Area Vaults/Intermediate-Level Tritium Vault.

f. Engineered low-level trenches.

g. Consolidated Incineration Facility.



F.5.2.2 Accident Analysis for the Low-Level Waste No-Action Alternative

This section addresses the effects of postulated Accidents associated with the no-action alternative for low-level waste. The postulated accidents provide a baseline for comparison of the effects of the postulated accidents associated with the other alternatives.

Impacts from Postulated Radiological Accidents

From the list of potential radiological Accidents presented in Table F-9, the representative bounding accident scenarios were identified for the no-action alternative through the binning process described in Section F.4.1. Figure F-3 identifies the highest-risk accident scenarios for the four frequency ranges. As shown in Figure F-3, most of the accidents were in the anticipated frequency range. This distribution of accidents is due to the levels of radioactivity associated with low-level waste. At the lower accident frequency ranges, the risks become quite small compared with those in the anticipated accident frequency range. Consequently, for the no-action alternative, it was not necessary to analyze an accident scenario beyond the extremely unlikely accident frequency range. Table F-10 lists the low-level waste representative bounding accidents, accident consequences, and latent fatal cancers for exposed workers and the public.

The low-level waste representative bounding Accidents and their impacts, as identified in Table F-10, are described below:

Accident Scenario 1 -Container breach at the intermediate-level nontritium vault (two containers, noncombustible waste): The intermediate-level nontritium vault would contain both combustible waste (paper, plastics, cloth, etc.) and noncombustible waste (scrap hardware) contaminated with mixed fission products. Accidents involving this scrap could result in the airborne release of this contamination. The major contributor to the dose would be the waste material, which becomes airborne as a result of the accident. In order to estimate the consequences of this accident, the following conservative assumptions were made:

- Two waste containers were breached. This assumption is based on the hypothetical situation in which one waste container was being placed (by crane) into the intermediate-level nontritium vault cell and was inadvertently dropped (through either human error or crane malfunction) on a second waste container already within the intermediate-level nontritium vault cell, resulting in a breach of both containers.

Figure F-3.

- Analysis has shown that the radionuclide release due to rupture of a waste container in the intermediate-level nontritium vault that contains a noncombustible waste form would conservatively bound the release of an intermediate-level nontritium vault container that contains a combustible waste form. Therefore, it is conservatively assumed for this analysis that the two damaged waste containers have noncombustible waste as their contents.

- Radiological container inventory for the intermediate-level nontritium vault is based on 120 percent of the maximum estimated value.

Accident Scenario 13 -High wind at the intermediate-level nontritium vault (one container): In a moderate hazard facility, DOE (LLNL 1990) specifies a maximum wind speed of 175 kilometers
(109 miles) per hour and a wind-driven missile in the form of a two-by-four plank weighing 6.8 kilograms (15 pounds) and traveling with a horizontal speed of 80 kilometers (50 miles) per hour at a maximum height of 9 meters (30 feet). The accident analyzed for this high­wind event is the breach of one container as the result of a wind-driven missile entering the open top of the intermediate-level nontritium vault and striking a waste container. It is assumed that 0.1 percent of the waste material becomes airborne. Analysis has shown that the radionuclide release would be the same as that for the container breach accident described above. Therefore, it is conservatively assumed that the high-wind-driven missile strikes containers that contain noncombustible waste.

Accident Scenario 15 -Tornado (220 kilometers per hour) at the intermediate-level nontritium vault (two containers): The accident analyzed for the 220-kilometer (137-mile) per hour tornado is the breach of two containers as the result of two tornado-driven missiles entering the open top of the intermediate-level nontritium vault and each striking one waste container, for a total of two failed containers. Analysis has shown that the radionuclide release would be the same as that for the container breach accident described above. Therefore, it is conservatively assumed that the tornado-driven missiles strike containers that contain noncombustible waste.


F.5.2.3 Accident Analysis for the Low-Level Waste Under Alternative B

This section addresses the impacts of postulated Accidents for low-level waste associated with alternative B.


F.5.2.3.1 Impacts from Postulated Radiological Accidents

This section presents the potential effects of postulated radiological Accidents at facilities identified in Table F-8 for the low-level waste management described in alternative B. Figure F-4 shows the highest-risk accident scenarios for the four frequency ranges. As shown in Figure F-4, most of the accidents analyzed were in the anticipated accident frequency range. The distribution of accidents analyzed is indicative of the levels of radioactivity associated with low-level waste. At the lower accident frequency ranges, the risks become quite small compared to those in the anticipated accident frequency range. Accidents associated with the Consolidated Incineration Facility occur in the less frequent accident ranges. Table F-11 lists the representative bounding accidents, accident consequences, and latent fatal cancers for exposed workers and the public. DOE assumes that conclusions regarding representative bounding accident scenarios could change as a result of the minimum, maximum, or expected waste forecasts. The accident analysis for each accident scenario is based on a conservative assumption of peak utilization of facilities. That is, the minimum, maximum, and expected waste forecasts would only affect how long the facilities would operate. Therefore, while the consequence or frequency of postulated accidents do not change, the expected duration of risk from a facility-specific accident scenario could be longer or shorter, depending on the case. The number of new facilities needed to meet the low-level waste management requirements could be affected by the minimum, maximum, and expected waste forecasts. Thus, the consequence or frequency of specific accident scenarios could be increased or decreased, depending on the case. Impacts for these cases will be addressed in the representative bounding accident descriptions.

Accident Scenario 1 -Container breach at the intermediate-level nontritium vault (two containers, noncombustible waste): This accident scenario is detailed in Section F.5.1.2. This accident scenario is considered the representative bounding accident for the anticipated accident range. Under the expected waste forecast, four additional intermediate-level waste vaults are expected to be required. For the minimum waste forecast with two additional intermediate-level waste vaults, it could be assumed that the frequency of this accident would be less than for the expected waste forecast. For the maximum waste forecast with nine additional intermediate-level waste vaults, it could be assumed that the frequency would be greater than for the expected waste forecast (i.e., more containers are at risk of a breach).

Accident Scenario 12 -Large fire at the Consolidated Incineration Facility: Most fires at the Consolidated Incineration Facility would be caused by welding, electrical shorts, friction, materials in contact with hot process equipment, and smoking. Other causes would include lightning and explosions. The consequences of such fires would be monetary losses, injuries and death to personnel, and

Figure F-4.

This accident scenario is considered the representative bounding accident for the unlikely accident range.

For alternative B -minimum, maximum, and expected waste forecasts, the Consolidated Incineration Facility would operate from 1996 to 2024 and the highest-risk accident in this frequency range would be Accident Scenario 13: High wind at the intermediate-level nontritium vault.

Accident Scenario 15 -Tornado [220 kilometers (137 miles) per hour] at the
intermediate-level nontritium vault: This accident scenario is detailed in Section F.5.2.2 and is considered the representative bounding accident for the extremely unlikely accident range.

Accident Scenario 24 -Explosion of tanks associated with the Consolidated Incineration Facility: Tanks located in the vicinity of the Consolidated Incineration Facility include two liquid waste blend tanks. These 16-cubic-meter (4,200-gallon) tanks receive wastes from various sources and blend them to a proper viscosity and heating value prior to feeding into the rotary kiln. Each tank is fitted with an agitator that continually mixes the waste and a heater that maintains the temperature. Fuel in the form of liquid waste is always present in the tanks. Potential ignition sources include a malfunction of the agitator or heater. Such a malfunction would have to include disintegration of an agitator impeller or an electrical short in the heater that overrode thermostatic control. A transfer error could also be an ignition source if highly incompatible materials were introduced into a tank. Lightning could be an ignition source if the tank was not properly grounded. Simultaneously, a nitrogen blanketing system would have to fail and oxygen would have to be introduced into the tank head space for an explosion to occur. Failure of the nitrogen blanketing system initiates visual and audible alarms and stops all tank-feed and transfer operations. Once the blanketing system failed, there would be a period of time before enough oxygen could diffuse into the tank head space to cause an explosion. This accident scenario is considered the representative bounding accident for the beyond-extremely-unlikely accident range.

For alternative B -minimum, maximum, and expected waste forecasts, the Consolidated Incineration Facility is expected to operate from 1996 to 2024. Technical reports identified no accidents from 1994 to 1996.


F.5.2.3.2 Impacts from New or Proposed Facilities

Table F-8 identifies two proposed facilities under alternative B for which no quantitative accident analyses exist. These facilities are listed and briefly described below. Because these facilities are proposed and their designs are not necessarily complete, quantitative analyses at this time would provide non-meaningful risk information (because the designs could be changed) that could be compared to the risk information available for existing facilities. However, DOE will perform quantitative analyses throughout the design, construction, and operation phases of the soil sort facility in accordance with requirements, and DOE will ensure that the risks associated with operating these facilities are within established regulatory guidelines.


The soil sort facilitywould sort and segregate clean and contaminated soils. This facility would provide standard sand-and-gravel-handling equipment with instrumentation for monitoring radiation. Radiation detectors would divert contaminated material traveling along a conveyer system in a different direction from the clean soil. By locating small particles of radioactive material dispersed throughout the soil, contaminants could be isolated and removed. It is assumed that the Accidents at the soil sort facility would be bounded by the accidents selected for alternative B.

Offsite smelter -DOE is currently studying the use of an offsite smelter to determine the economic feasibility of recycling low-level contaminated stainless-steel scrap obtained during the decommissioning of retired SRS facilities. The intended end products of the stainless-steel recycling process are containers [2.83-cubic meter (100-cubic foot) boxes and 55-gallon drums] for the disposal or storage of radioactive waste originating within the DOE complex. Since no decisions on siting, configuration of equipment, or even whether the project would be completed have been made at this time, DOE assumes that Accidents involving an offsite smelter would be bounded by the accidents selected for alternative B.

Offsite low-level waste volume reduction ñ DOE plans to use an offsite vendor to supercompact, repackage, or incinerate low-level waste. None of the potential Accidents involving low-level waste identified in Table F-9 occurred at the compactor facilities. Accidents identified for low-level waste at the Consolidated Incineration Facility were not representative bounding accidents. Therefore, DOE assumes that accidents involving an offsite volume-reduction facility would be bounded by the accidents selected for alternative B.


F.5.2.4 Accident Analysis for Low-Level Waste Under Alternative A

Alternative A emphasizes a limited treatment configuration. Its accident analysis is the same as that for the no-action alternative. The facilities under alternative A are identical to the facilities identified to support the no­action alternative. The impacts from the postulated radiological accident scenarios are the same as described in Section F.5.2.2 (Figure F­3).


F.5.2.5 Accident Analysis for Low-Level Waste Under Alternative C

Alternative C emphasizes an extensive treatment configuration. The facilities listed in Table F-8 for alternative C are similar to those that support alternative B for low-level waste, except that alternative C includes a proposed non-alpha vitrification facility. Since this facility does not present a representative bounding accident, the effects from the postulated radiological accident scenarios for alternative C are identical to those for alternative B, as described in Section F.5.2.3 (Figure F-4). A qualitative evaluation of the impacts associated with the non-alpha vitrification facility is as follows:

Non-alpha vitrification facility -The non-alpha vitrification facility would prepare waste for vitrification, vitrify it, and treat the secondary waste gases and liquids generated by the vitrification process. The waste would fall in the following treatability groups: soils, job-control waste, and equipment. The facility would consist of a thermal pretreatment unit, a melter, and an offgas treatment unit. The afterburner would enhance destruction of any remaining hazardous organic compounds prior to treatment in the offgas system. It can be assumed that the accident initiators for the non-alpha vitrification facility would be similar to those for the Defense Waste Processing Facility vitrification facility. However, the releases would be minor in comparison. It is also assumed that the offgas treatment unit Accidents would be similar to those for the F/H-Area Effluent Treatment Facility.


F.5.2.6 Impacts to Involved Workers from Accidents Involving Low-Level Waste

The representative bounding accident scenarios for low-level waste involve the intermediate level nontritium waste vaults, the long-lived waste storage buildings, and the Consolidated Incineration Facility. For the intermediate level nontritium vaults, scenarios involve a container rupture, a tornado, and a high wind accident scenario. For the container-rupture scenario, dose contribution from direct radiation exposure is not considered major because operations are carried out remotely. The following features are provided to control exposure and limit injuries to workers due to container rupture:

- The crane operator is shielded from waste containers.

- The crane operator has dosimetry with an audible alarm that sounds when a preset dose is reached.

- The waste container lifting-fixtures are remotely controlled from the crane control cab.

- Cell covers are installed over partially filled cells to provide radiation shielding.

- The cell cover lifting-fixture is remotely controlled from the crane control cab and the shielding plugs are remotely engaged and disengaged.

Because high winds and tornadoes can usually be predicted and proper precautions taken before major damage occurs, radiological and/or chemical effects to the facility workers due to high winds or tornadoes are considered to be minor. Procedures exist to discontinue operation and place waste containers in safe temporary storage areas in cases of inclement weather.

For the long-lived waste storage buildings accident scenario, a fire involving a dropped deionizer vessel was identified as the representative bounding accident. Although workers would only be expected to be in the immediate vicinity of the long-lived waste storage buildings during waste handling operations, they would be exposed to occupational and industrial types of injuries associated with a fire and could possibly receive a dose due to exposure to radioactive materials.

The accident scenarios for the Consolidated Incineration Facility involve a fire or explosion. The consequences to facility workers from either a fire or explosion in the immediate area include occupational and industrial types of injuries (possibly including death) as well as doses resulting from contact with radioactive materials.

While some exposure to involved workers could occur due to an accidental release of radioactive materials in all scenarios, DOE assumes no fatalities to workers would be likely from radiological consequences.


F.5.2.7 Impacts from Low-Level Waste Chemical Accidents

No chemical hazards assessment was performed for the low-level radioactive waste facilities. The chemical inventories for each facility that has hazard assessment documentation were compared to the reportable quantities as listed in 40 CFR Part 302.4. None of the facilities has sufficient quantities of hazardous chemicals to warrant a complete chemical analysis.


F.5.3 HAZARDOUS WASTE


Identification of Hazardous Waste Facilities

The accident analyses considered facilities and processes that support the management of hazardous waste. The facilities were identified from the hazardous waste information provided in Chapter 2.
Table F-12 lists the facilities associated with each of the alternatives. Descriptions of these facilities are provided in Appendix B.

Although Table F-12 identifies several nuclear facilities (e.g., Consolidated Incineration Facility), there are no radiological Accidents associated with hazardous waste. Radiological material with a hazardous waste component was identified as mixed waste and is addressed in Section F.5.4.

Since mixed waste facilities contain radioactive materials with a hazardous chemical component, and in some cases, results of the accident scenarios for mixed waste bound the chemical hazards at hazardous waste facilities, impacts from chemical hazards for hazardous waste are addressed in Section F.5.4.7 for mixed waste.



Table F-10. Representative bounding radiological accidents for low-level waste under the no-action alternative.


Point estimate of increased risk per yeara
(increased risk of fatal cancers per occurrence)b
Accident consequences
Latent fatal cancers







No.







Accident description




Frequency per year

(accident range)




Uninvolved worker at 100 meters
(rem)




Uninvolved worker at 640 meters
(rem)
Offsite maximally exposed individual (rem)




Population within 80 kilometersc
(person-rem)





Uninvolved worker at 100 meters





Uninvolved worker at 640 meters




Offsite maximally exposed individual





Population within 80 kilometers
1Container breach at the ILNTVd

2.00E-02

(anticipated)
6.47E+012.30E+00 3.31E-021.68E+03 1.04E-03
(5.18E-02)
1.84E-05
(9.20E-04)
3.31E-07
(1.66E-05)
1.68E-02
(8.40E-01)
13High wind at the ILNTVd

1.00E-03

(unlikely)
1.01E-036.08E-04 3.04E-042.11E+01 4.04E-10

(4.04E-07)

2.43E-10

(2.43E-07)

1.52E-10

(1.52E-07)

1.06E-05

(1.06E-02)

15Tornado at the ILNTVd

2.00E-05

(extremely unlikely)
4.07E-047.73E-02 1.18E-021.18E+01 3.26E-12

(1.63E-07)

6.18E-10

(3.09E-05)

1.18E-10

(5.90E-06)

1.18E-07

(5.90E-03)

a. Point estimate of increased risk per year is calculated by multiplying the consequence (dose) ¥ latent cancer conversion factor ¥ annual frequency.

b. Increased risk of fatal cancers per occurrence is calculated by multiplying the consequence (dose) ¥ latent cancer conversion factor.

c. A conservative assumption of 99.5 percentile meteorology was assumed for determining accident consequences for the exposed population within 80 kilometers. A less conservative meteorology (50 percentile) was used to determine the accident consequences for exposed individuals.

d. Intermediate-Level Non-Tritium Vault.



Table F-11. Representative bounding radiological accidents for low-level waste under alternative B.


Point estimate of increased risk per yeara
(increased risk of fatal cancers per occurrence)b
Accident consequences
Latent fatal cancers







No.







Accident description




Frequency per year

(accident range)




Uninvolved worker at 100 meters
(rem)




Uninvolved worker at 640 meters
(rem)
Offsite maximally exposed individual (rem)




Population within 80 kilometersc
(person-rem)





Uninvolved worker at 100 meters





Uninvolved worker at 640 meters




Offsite maximally exposed individual





Population within 80 kilometers
1Container breach at the ILNTVd

2.00E-02

(anticipated)
6.47E+012.30E+00 3.31E-021.68E+03 1.04E-03
(5.18E-02)
1.84E-05
(9.20E-04)
3.31E-07
(1.66E-05)
1.68E-02
(8.40E-01)
12Large fire at CIFe

2.34E-04

(unlikely)
2.55E+008.15E-02 1.40E-039.58E+01 2.39E-07

(1.02E-03)

7.63E-09

(3.26E-05)

1.64E-10

(7.00E-07)

1.12E-05

(4.79E-02)

15Tornado at the ILNTVd


2.00E-05

(extremely unlikely)
4.07E-047.73E-02 1.18E-021.18E+01 3.26E-12

(1.63E-07)

6.18E-10

(3.09E-05)

1.18E-10

(5.90E-06)

1.18E-07

(5.90E-03)

24Explosion at CIFe - tank farm


3.40E-07

(beyond- extremely- unlikely)
1.28E+004.07E-02 7.01E-044.79E+01 1.74E-10

(5.12E-04)

5.54E-12

(1.63E-05)

1.19E-13

(3.51E-07)

8.14E-09

(2.40E-02)

a. Point estimate of increased risk per year is calculated by multiplying the consequence (dose) ¥ latent cancer conversion factor ¥ annual frequency.

b. Increased risk of fatal cancers per occurrence is calculated by multiplying the consequence (dose) ¥ latent cancer conversion factor.

c. A conservative assumption of 99.5 percentile meteorology was assumed for determining accident consequences for the exposed population within 80 kilometers. A less conservative meteorology (50 percentile) was used to determine the accident consequences for exposed individuals.

d. Intermediate-Level Non-Tritium Vault.

e. Consolidated Incineration Facility.



Table F-12. Hazardous waste facilities identified by alternative.






List of facilities



No-action alternative


Alternative A (limited treatment configuration)
Alternative C (extensive treatment configuration)
Alternative B
(moderate treatment configuration)
Hazardous wasteHazardous waste storage facilities
X
X
X
X
M-Area Air Stripper
X
X
X
X
Recycle unitsa
X
X
X
X
Containment buildingb,c   
X
 
Non-alpha vitrification facilityb   
X
 
Consolidated Incineration Facility  
X
Xd
X

a. Recycle units include silver recovery, refrigerant recycle, lead melter, and solvent distillation. These units do not have quantitative or qualitative accident analyses available. Accidents for recycle units are assumed to be bounded by the accident scenarios selected for this alternative.

b. Proposed facility.

c. Accidents for the containment building are assumed to be the same as those identified for the Hazardous Waste/Mixed Waste Treatment Building identified in the technical report presenting accident analyses for solid wastes (WSRC 1994c).

d. Facility operates until proposed facility comes on line.



F.5.4 MIXED WASTE


The following evaluation addresses the impacts of postulated Accidents associated with the alternatives considered in this eis for the management of mixed waste.


F.5.4.1 Facilities and Accidents: Mixed Waste

The accident analyses considered facilities and processes that support the management of mixed waste. The facilities were identified from the mixed waste information provided in Chapter 2. Table F-13 lists the facilities associated with each of the alternatives. Descriptions of these facilities are provided in Appendix B. For each facility, a list of postulated-accident scenarios was developed to support the accident analysis for each mixed waste alternative. Accidents for RCRA disposal are assumed to be the same as those identified for the Hazardous Waste/Mixed Waste Disposal Facility vaults. The design of these vaults (concrete vaults with temporary steel covers) and their operations (waste containers are transferred from trucks to the vaults via overhead crane) are similar to that of the intermediate-level waste vaults. The postulated-accident scenarios for the intermediate-level nontritium vaults are assumed to bound the impacts of postulated Accidents for RCRA disposal.

Table F-14 lists potential Accidents . This information was extracted from the technical reports supporting this eis (WSRC 1994b, c, and e). While all the accidents listed in Table F-14 are supported by quantitative analyses, they are not listed in this table because accident impacts for proposed facilities are mainly qualitative.



Table F-13. Mixed-waste facilities identified by alternative.






List of facilities areaa



No-action alternative


Alternative A (limited treatment configuration)


Alternative C (extensive treatment configuration)
Alternative B
(moderate treatment configuration)
Organic waste storage tank
X
X
X
X
F/H-Area Effluent Treatment Facility

X


X


X


X
Mixed waste storage facilities
X
X
X
X
Solvent storage tanks
S29-S30 and S33-S36
X
X
X
X
Aqueous and Organic waste storage tanks
X
   
SRTC mixed waste storage tanks exchange
X
X
X
X
M-Area Vendor Treatment Facility
X
X
X
X
RCRA disposala
X
X
X
X
Process Waste Interim Treatment Facility (Bldg. 341­1M)  
X
X
X
Containment buildingb,c  
X
X
X
Non-alpha vitrification facilityb   
X
X
Soil sort facilityb  
X
  
Consolidated Incineration Facility  
X
Xd
X
Dilute Effluent Treatment Facility (Bldg. 341-M)  
X
X
X

a. Accidents for Resource Conservation and Recovery Act (RCRA) disposal are assumed to be the same as those identified for the Hazardous Waste/Mixed Waste Disposal Facility vaults identified in the technical report (WSRC 1994c).

b. Proposed facility.

c. Accidents for the containment building are assumed to be the same as those identified for the Hazardous Waste/Mixed Waste Treatment Building identified in the technical report presenting accident analyses for solid wastes (WSRC 1994c).

d. Facility operates until proposed facility comes on line.



F.5.4.2 Accident Analysis for the Mixed Waste No-Action Alternative

This section addresses the impacts of postulated accidents associated with the no­action alternative for treating mixed waste. The postulated accidents provide a baseline for comparison of the effects of the postulated accident associated with the action alternatives.



Table F-14. List of potential Accidents associated with the management of mixed waste.



No.


Accident description
Annual
frequency
Dosea
(rem)
RiskRisk (rem/yr)
1
Container breach at the eaV/ILNTVb
2.00E-02
2.63E-01
5.26E-03
2
Fire at the eaV/ILNTVb
8.30E-02
8.60E-03
7.14E-04
3
Excessive open containers at the containment building
1.00E-02
5.68E-02
5.68E-04
4
Release due to multiple open containers at the containment building
3.00E-03
6.81E-02
2.04E-04
5
Excessive inventory at the containment building
5.00E-03
3.20E-02
1.60E-04
6
Earthquake at the containment building
1.50E-03
6.20E-02
9.30E-05
7
Drum spill and tritiumtritium release at the containment building
5.00E-03
1.60E-02
8.00E-05
8
Tornado at the containment building
2.00E-02
3.05E-03
6.10E-05
9
Release due to one open container at the containment building
7.74E-03
6.20E-03
4.80E-05
10
Evaporation/dispersal of two to ten containers at the containment building
2.00E-04
6.00E-02
1.20E-05
11
Earthquake at the SRTCc storage tanks
2.00E-04
5.84E-02
1.17E-05
12
F2 tornado at Building 316-M
1.12E-04
5.67E-02
6.35E-06
13
Earthquake (0.04g) at Building 316-M
2.00E-03
1.65E-03
3.30E-06
14
F3 tornado at Building 316-M
2.80E-05
1.18E-01
3.30E-06
15
High wind at the containment building
2.00E-02
1.53E-04
3.06E-06
16
Large fire for entire CIFd
2.34E-04
1.07E-02
2.50E-06
17
F4 tornado at Building 316-M
3.50E-06
4.72E-01
1.65E-06
18
Drop/Spill/Leak at the SRTCc storage tanks
1.50E-02
6.52E-05
9.77E-07
19
High wind at the eaV/ILNTVb
1.00E-03
3.40E-04
3.40E-07
20
Earthquake at CIFd
1.00E-03
2.65E-04
2.65E-07
21
Explosion at CIFd - rotary kiln
1.50E-04
1.57E-03
2.36E-07
22
Tornado at the eaV/ILNTVb
2.00E-05
1.18E-02
2.36E-07
23
High velocity straight winds at CIFd
2.00E-02
5.23E-06
1.05E-07
24
Explosion at the containment building containment buildingreleasing 50 percent of tritiumtritium inventory
1.00E-06
5.58E-02
5.58E-08
25
Fire at the containment building containment buildingreleasing 50 percent of tritiumtritium inventory
1.00E-06
5.58E-02
5.58E-08
26
Release at Building 341-1M Building due to earthquake
2.00E-04
1.54E-04
3.08E-08
27
Explosion at CIFd - backhoe housing
4.00E-04
5.64E-05
2.26E-08
28
Normal processing with tritiumtritium ETFe airborne release due to straight wind
1.20E-03
1.47E-05
1.76E-08
29
Normal processing other than tritiumtritium ETFe airborne release due to straight wind
1.20E-03
1.46E-05
1.75E-08
30
Rainwater flooding at the containment building
1.00E-06
1.60E-02
1.60E-08
31
Normal processing with tritiumtritium ETFh liquid release due to straight wind
1.20E-03
9.40E-06
1.13E-08
32
Aircraft crash into the containment building
1.60E-07
6.78E-02
1.08E-08
33
Normal processing other than tritiumtritium ETFe liquid release due to straight wind
1.20E-03
7.70E-06
9.24E-09
34
Normal processing with tritiumtritium ETFe airborne release due to tornado
4.50E-05
2.04E-04
9.18E-09
35
Normal processing other than tritiumtritium ETFe airborne release due to tornado
4.50E-05
2.03E-04
9.14E-09
36
Normal processing with tritiumtritium ETFe airborne release due to earthquake
2.00E-04
2.77E-05
5.54E-09

Table F-14. (continued).



No.


Accident description
Annual
frequency
Dosea
(rem)
RiskRisk (rem/yr)
37
Normal processing with tritiumtritium ETFe liquid release due to earthquake
2.00E-04
9.40E-06
1.88E-09
38
Explosion at CIFd - tank farm tank
3.40E-07
5.36E-03
1.82E-09
39
Normal processing other than tritiumtritium ETFe liquid release due to earthquake
2.00E-04
7.70E-06
1.54E-09
40
Explosion at CIFd - tank farm sump and diked area
1.90E-07
6.85E-03
1.30E-09
41
Normal processing other than tritiumtritium ETFe airborne release due to earthquake
2.00E-04
2.50E-06
5.00E-10
42
Design basis ETFe liquid release due to straight wind
9.84E-06
4.70E-05
4.62E-10
43
Normal processing with tritiumtritium ETFe liquid release due to tornado
4.50E-05
9.40E-06
4.23E-10
44
Normal processing other than tritiumtritium ETFe liquid release due to tornado
4.50E-05
7.70E-06
3.47E-10
45
Design basis ETFe airborne release due to straight wind
9.84E-06
1.12E-05
1.10E-10
46
Design basis ETFe airborne release due to tornado
3.69E-07
2.83E-04
1.04E-10
47
Normal processing with tritiumtritium ETFe airborne release due to transfer error
1.80E-02
4.46E-09
8.03E-11
48
Design basis ETFe liquid release due to earthquake
1.64E-06
4.70E-05
7.71E-11
49
Normal processing with tritiumtritium ETFe airborne release due to corrosion damage
8.80E-02
8.75E-10
7.70E-11
50
Normal processing other than tritiumtritium ETFe airborne release due to transfer error
1.80E-02
1.72E-09
3.10E-11
51
Normal processing other than tritiumtritium ETFe airborne release due to corrosion damage
8.80E-02
3.38E-10
2.97E-11
52
Design basis ETFe airborne release due to leaks
2.13E-02
1.35E-09
2.88E-11
53
Release at DETFf due to earthquake
2.00E-03
1.17E-08
2.34E-11
54
Design basis ETFe airborne release due to overflow
1.48E-03
1.44E-08
2.13E-11
55
Design basis ETFe liquid release due to tornado
3.69E-07
4.70E-05
1.73E-11
56
Design basis ETFe airborne release due to earthquake
1.64E-06
8.40E-06
1.38E-11
57
Normal processing with tritiumtritium ETFe airborne release due to a siphoning incident
2.60E-03
1.12E-09
2.91E-12
58
Design basis ETFe airborne release due to spill
1.48E-03
1.88E-09
2.78E-12
59
Normal processing other than tritiumtritium ETFe airborne release due to siphoning incident
2.60E-03
4.34E-10
1.13E-12
60
Design basis ETFe airborne release due to transfer error
1.48E-04
6.86E-09
1.02E-12
61
Design basis ETFe airborne release due to corrosion damage
7.22E-04
1.35E-09
9.75E-13
62
Design basis ETFe airborne release due to a siphoning incident
2.13E-05
1.73E-09
3.68E-14

a. The dose given is for the offsite maximally exposed individual using 99.5 percentile meteorology.

b. Intermediate-level nontritium vault.

c. Savannah River Technology Center.

d. Consolidated Incineration Facility.

e. F/H-Area Effluent Treatment Facility.

f. Dilute Effluent Treatment Facility (Bldg. 341-M).



Table F-15. Representative bounding radiological accidents for the no-action alternative for mixed wastes.


Point estimate of increased risk per yeara
(increased risk of fatal cancers per occurrence)b
Accident consequences
Latent fatal cancers







No.







Accident description




Frequency per year

(accident range)




Uninvolved worker at 100 meters
(rem)




Uninvolved worker at 640 meters
(rem)



Offsite maximally exposed individual (rem)




Population within 80 kilometersc
(person-rem)





Uninvolved worker at 100 meters





Uninvolved worker at 640 meters




Offsite maximally exposed individual





Population within 80 kilometers
1Container breach at the ILNTVd

2.00E-02

(anticipated)
6.47E+012.30E+00 3.31E-021.68E+03 1.04E-03
(5.18E-02)
1.84E-05
(9.20E-04)
3.31E-07
(1.66E-05)
1.68E-02
(8.40E-01)
11Earthquake at the SRTCe Storage Tanks
2.00E-04

(unlikely)
6.00E+001.92E-01 8.06E-033.60E+01 4.80E-07

(2.40E-03)

1.54E-08

(7.68E-05)

8.06E-10

(4.03E-06)

3.60E-06

(1.80E-02)

14F3 tornadof at Building 316-M 2.80E-05

(extremely unlikely)
4.78E-041.15E-01 1.18E-017.98E-02 5.35E-12

(1.91E-07)

1.29E-09

(4.60E-05)

1.65E-09

(5.90E-05)

1.12E-09

(3.99E-05)

46Design basis ETFg airborne release due to tornado 3.69E-07

(beyond- extremely- unlikely)
2.17E-036.91E-05 3.90E-053.44E-04 3.20E-13

(8.68E-07)

1.02E-14

(2.76E-08)

7.20E-15

(1.95E-08)

6.35E-14

(1.72E-07)

a. Point estimate of increased risk per year is calculated by multiplying the consequence (dose) ¥ latent cancer conversion factor ¥ annual frequency.

b. Increased risk of fatal cancers per occurrence is calculated by multiplying the consequence (dose) ¥ latent cancer conversion factor.

c. A conservative assumption of 99.5 percentile meteorology was assumed for determining accident consequences for the exposed population within 80 kilometers. A less conservative meteorology (50 percentile) was used to determine the accident consequences for exposed individuals.

d. Intermediate-Level Non-Tritium Vault.

e. Savannah River Technology Center.

f. F3 tornadoes have rotational wind speeds of 254 to 331 kilometers (158 to 206 miles) per hour.

g Effluent Treatment Facility.


Table F-16. Representative bounding radiological accidents for mixed wastes under alternative B.


Point estimate of increased risk per yeara
(increased risk of fatal cancers per occurrence)b
Accident consequences
Latent fatal cancers







No.







Accident description




Frequency per year

(accident range)




Uninvolved worker at 100 meters
(rem)




Uninvolved worker at 640 meters
(rem)
Offsite maximally exposed individual (rem)




Population within 80 kilometersc
(person-rem)





Uninvolved worker at 100 meters





Uninvolved worker at 640 meters




Offsite maximally exposed individual





Population within 80 kilometers
1Container breach at the ILNTVd

2.00E-02

(anticipated)
6.47E+012.30E+00 3.31E-021.68E+03 1.04E-03
(5.18E-02)
1.85E-05
(9.20E-04)
3.31E-07
(1.66E-05)
1.68E-02
(8.40E-01)
4Release due to multiple open containers at the containment building

3.00E-03

(unlikely)
3.91E-015.76E-01 8.13E-033.80E+02 4.69E-07
(1.56E-04)
6.91E-07
(2.30E-04)
1.22E-08
(4.07E-06)
5.70E-04
(1.90E-01)
14F3 tornadoe at Building 316-M


2.80E-05

(extremely unlikely)
4.78E-041.15E-01 1.18E-017.98E-02 5.35E-12

(1.91E-07)

1.29E-09

(4.60E-05)

1.65E-09

(5.90E-05)

1.12E-09

(3.99E-05)

32Aircraft crash at the containment building

1.60E-07

(beyond-extremely-unlikely)
1.52E+015.41E-01 8.32E-033.99E+02 9.73E-10
(6.08E-03)
3.46E-11
(2.16E-04)
6.66E-13
(4.16E-06)
3.19E-08
(2.00E-01)

a. Point estimate of increased risk per year is calculated by multiplying the consequence (dose) ¥ latent cancer conversion factor ¥ annual frequency.

b. Increased risk of fatal cancers per occurrence is calculated by multiplying the consequence (dose) ¥ latent cancer conversion factor.

c. A conservative assumption of 99.5 percentile meteorology was assumed for determining accident consequences for the exposed population within 80 kilometers. A less conservative meteorology (50 percentile) was used to determine the accident consequences for exposed individuals.

d. Intermediate-Level Non-Tritium Vault.

e. F3 tornadoes have rotational wind speeds of 254 to 331 kilometers (158 to 206 miles) per hour.



F.5.4.2.1 Impacts from Postulated Radiological Accidents

From the list of potential radiological Accidents presented in Table F-14, the representative bounding accident scenarios were identified for the no­action alternative using the binning process described in Section F.4.1. Figure F-5 shows the highest-risk accident scenarios for the various frequency ranges for the no-action alternative. As shown in Figure F-5, the accidents associated with mixed waste are analyzed over a broad spectrum of consequences and frequencies. The accident scenarios postulated for the F/H-Area Effluent Treatment Facility generally present lower consequences, while accident scenarios postulated for vault disposal facilities generally present higher consequences. Table F­15 lists the representative bounding accidents, accident consequences, and latent fatal cancers for exposed workers and the public.

Accident Scenario 1 -Container breach at the intermediate-level nontritium vault (two containers, noncombustible waste): This accident scenario is detailed in Section F.5.2.2 and is assumed to be representative of a mixed waste accident for vault disposal.

Accident Scenario 11 -Earthquake at the Savannah River Technology Center storage tanks: The earthquake (greater than 0.2g) is assumed to impose reaction loads on the above-grade confinement structure and damage the structure. The below-grade structures, including the tank cells, are expected to respond with the ground motion, so major damage is considered unlikely. Similarly, because of their wall thickness [1.27 centimeters (0.5 inch) stainless steel], short height [3.35 to 3.96 meters (11 to 13 feet)], and small diameter [3 to 3.66 meters (10 to 12 feet)], it is unlikely that the tanks would rupture. However, in this scenario, the tank and cell exhaust filtration is assumed to be disrupted. This disruption is accounted for by assuming that the inventory of two 13.6-cubic-meter (3,600­gallon) high-activity waste tanks is available for airborne release. It is estimated that 0.1 percent of the radionuclides contained in the tank becomes airborne.

Accident Scenario 14 -F3 tornado at Building 316-M: Building 316-M (mixed waste storage building) is an outdoor storage area on a concrete base, with a roof and no sidewalls. Waste is stored in approved containers, generally 55-gallon drums and large steel boxes. Based on a similar analysis for the Burial Ground, an F3 tornado [a tornado with rotational windspeeds of 254 to 331 kilometers (158 to 206 miles) per hour] is assumed to rupture 25 percent of the drums. It is assumed that 100 percent of the drum contents could be scattered.

Accident Scenario 46 -Design basis F/H-Area Effluent Treatment Facility airborne release due to tornado: This accident scenario is detailed in Section F.5.1.2.1.

Figure F-5.


F.5.4.2.2 Impacts from New or Proposed Facilities

Table F-13 identifies no new or proposed facilities for the hazardous and mixed waste no-action alternative.


F.5.4.3 Accident Analysis for the Mixed Waste Under Alternative B


This section addresses the impacts of postulated Accidents associated with alternative B for mixed wastes.


F.5.4.3.1 Impacts from Postulated Radiological Accidents

This section presents potential effects from postulated radiological Accidents at facilities identified in Table F-13 for the management of mixed waste under alternative B. Figure F­6 shows the highest-risk accident scenarios for the various frequency ranges. As shown in Figure F-6, the accidents associated with mixed waste are analyzed over a broad spectrum of consequences and frequencies. The accident scenarios postulated for the F/H-Area Effluent Treatment Facility generally present lower consequences, while accident scenarios postulated for vault disposal facilities generally present higher consequences. Table F­16 lists the representative bounding accidents, accident consequences, and latent fatal cancers for exposed workers and the public for alternative B. DOE assumes that conclusions regarding representative bounding accident scenarios could change based on the minimum, maximum, and expected waste forecasts. The accident analyses for the accident scenarios are based on a conservative assumption of peak utilization of facilities [i.e., the minimum, maximum, and expected waste forecasts would only affect how long the facilities (e.g., the Consolidated Incineration Facility)] would operate. Therefore, while the consequence or frequency for postulated accidents do not change, the expected duration of risk from a facility-specific accident scenario could be longer or shorter, depending on the case. The number of new facilities needed to meet the mixed waste management requirements could be affected by the minimum, maximum, and expected waste forecasts. Thus, the consequence or frequency for specific accident scenarios could be increased or decreased, depending on the case. Impacts for the three cases are addressed in the representative bounding accident descriptions.

Figure F-6.

The representative bounding Accidents and their impacts under the alternative B are briefly described below:

Accident Scenario 1 -Container breach at the intermediate-level nontritium vault (two containers, noncombustible waste): This accident scenario is described in Section F.5.2.2 and is considered to be the representative bounding accident for the anticipated accident range.

Accident Scenario 4 -Release due to multiple (2 to 10) open containers at the containment building: The consequences of this accident scenario are bounded by the worst unmitigated accident scenario where the ventilation and scrubber systems of the containment building are assumed to fail. This accident scenario is considered the representative bounding accident for the unlikely accident range. Under the minimum, maximum, and expected waste forecasts, the containment building is expected to operate from 2006 to 2024. From 1994 to 2006 -- when the containment building is not operational -- the highest-risk accident in this frequency range would be Accident Scenario 18: Earthquake at the Savannah River Technology Center Storage Tanks.

Accident Scenario 14 -F3 tornado at Building 316-M: This accident scenario is detailed in Section F.5.4.2.1 and is considered the representative bounding accident for the extremely unlikely accident range. Utilization of this facility is expected to be the same under the minimum, maximum, and expected waste forecasts.

Accident Scenario 32 -Aircraft crash at the containment building: An aircraft could breach only that part of the containment building into which it crashes. DOE assumes that the consequences associated with this event are the same as for the worst unmitigated accident event for the entire containment building. Thus, whether one or all segments in the containment building are breached due to an aircraft crash, the consequences listed for this scenario are considered to be bounding. This accident scenario is considered the representative bounding accident for the beyond-extremely-unlikely-accident range. Under the minimum, maximum, and expected waste forecasts, the containment building is expected to operate from 2006 to 2024. From 1994 to 2006, the next highest risk accident in this frequency range would be Accident Scenario 50: Explosion at the Consolidated Incineration Facility tank farm sump and diked area.


F.5.4.3.2 Impacts from New or Proposed Facilities

Table F-13 identifies three proposed facilities under alternative B for which no quantitative accident analyses exist. Accidents associated with the soil sort facilityare described in Section F.5.2.3.2 and with the non-alpha vitrification facility in Section F.5.2.5.


F.5.4.4 Accident Analysis for Mixed Waste Under Alternative A

The facilities listed in Table F-13 for alternative A are identical to those that support alternative B, except that alternative A does not include the non-alpha vitrification facility. Since this facility was not involved in the representative bounding accident, the effects from the postulated radiological accident scenarios for alternative A are identical to those described in Section F.5.4.3.


F.5.4.5 Accident Analysis for Mixed Waste Under Alternative C

The facilities listed in Table F-13 for alternative C are similar to those that support alternative B for mixed waste, except that the Consolidated Incineration Facility does not operate for the entire 30-year period under alternative C. Since this facility was not involved in the representative bounding accident, the effects from the postulated radiological accident scenarios for alternative C are identical to those described in Section F.5.4.3.


F.5.4.6 Impacts to Involved Workers from Accidents Involving Mixed Waste

The mixed waste Accidents that have the highest risks involve the containment building. The accident initiators (aircraft crash, explosion, or tornado) are considered to be more dangerous to the worker than the resulting release of contaminants. The other accident scenarios (transfer errors or container damage) are not expected to cause serious injury to workers, because the operators will be equipped with a breathing supply via an air compressor airflow. An emergency supply of breathing air is provided for each worker from high pressure breathing air cylinders permanently connected to the breathing air systems.


F.5.4.7 Impacts from Mixed Waste Chemical Accidents

Because the mixed waste facilities contain radioactive materials with a hazardous chemical component, the results of the mixed waste accident scenarios bound the chemical hazards at hazardous waste facilities. This section discusses the chemical hazards for mixed wastes, as well as those for hazardous wastes.

A chemical hazards analysis was performed for the Consolidated Incineration Facility as part of a safety analysis report. The basis for this analysis was that the chemical inventory would be such that an unmitigated release of all the material in one section of the facility would result in concentrations of chemicals at 100 meters (328 feet) less than one-half the concentration that is immediately dangerous to life and health (IDLH). The Consolidated Incineration Facility is considered a low hazard facility. The criteria for being a low hazard facility include the requirement that the nonradiological consequences associated with the highest accident frequencies are no greater than the specified IDLH value at 100 meters and 10 percent of the specified IDLH value at the SRS boundary. As reported in the technical report (WSRC 1994c), if releases are maintained below the IDLH onsite criterion, the releases are automatically below the IDLH offsite criterion. Since chemical inventories are controlled such that the worst-case nonradiological consequences can be no greater than 50 percent of the specified IDLH value at 100 meters (328 feet), both criteria are satisfied for the Consolidated Incineration Facility. As a result, further analysis is not necessary.

Preliminary chemical hazards analyses were performed for the E-Area mixed waste storage building, the N­Area mixed waste and hazardous waste storage buildings, and the B-Area hazardous waste storage building to determine the hazard categorization for each facility. The N­Area mixed waste and hazardous waste storage buildings have an inventory that bounds the E­Area mixed waste storage building and the B­Area hazardous waste storage building. The N-Area chemicals requiring further analysis to determine the potential consequences of their accidental release are listed in Table F-17. This table provides the maximum onsite and offsite airborne concentrations resulting from a postulated release of chemical inventory.

The Organic Waste Storage Tank associated with the Defense Waste Processing Facility would be the primary facility for the storage of benzene mixed waste. Benzene that has been separated from a precipitate slurry by distillation in the Defense Waste Processing Facility would be transferred approximately 112.7 meters (370 feet) to the Organic Waste Storage Tank in an above-ground pipe. Consequently, an explosion could occur in either the inner or outer tank or as a result of a benzene leak during a transfer. An explosion in either tank would occur if the oxygen concentration in the tank vapor space reaches the minimum required for combustion and the benzene vapor is ignited. A benzene release from the transfer line would form a pool on the ground, which would evaporate and form a vapor cloud. If ignited, the explosion of the vapor cloud could cause the Organic Waste Storage Tank to explode.

In a tornado scenario, the Organic Waste Storage Tank is assumed to catastrophically fail as the result of a tornado-generated missile. As the benzene leaves the tank, "splashing" occurs, causing a fraction of the benzene to become an aerosol. The released benzene forms a pool [122 meters by 122 meters (400 feet by 400 feet)] bounded by the drainage ditch that surrounds the organic waste storage tank site. The tornado is assumed to remain in the vicinity of the pool for one minute. The evaporation rate from the pool during this minute is based on a tornado wind speed of 177 kilometers (110 miles) per hour.

Following the tornado, evaporation from the pool continues over the next 4 minutes under normal wind conditions of 10 miles per hour. It is assumed that after 5 minutes from the initial failure of the Organic Waste Storage Tank, the released benzene has completely drained to the drainage ditch. It is also assumed that normal wind conditions continue for the remainder of the event. Table F­18 presents the results for the two postulated Organic Waste Storage Tank chemical accident scenarios.

Safety documentation does not analyze potential events involving hazardous materials at M­Area facilities. Using the methodology described in Section F.4.2 for M-Area facilities, it was determined that the inventory of sulfuric acid located in the Dilute Effluent Treatment Facility (341­M) would be the only chemical present in sufficient quantities to warrant further evaluation. This accident scenario assumed an unmitigated liquid spill of the entire inventory of sulfuric acid at 341-M, with a resulting pool covering 77 square meters (829 square feet) at a depth of 1 centimeter (0.39 inch). The evaporation rate for this liquid spill was estimated to be 2.01E-05 grams per second at standard pressure and temperature. The results of this chemical analysis are presented in Table F-19.



Table F-17. Mixed/hazardous waste chemical hazards analysis results.





Chemical


Quantity (kg)b
Onsite concentration
100 meters (328 feet) (mg/m3)
c
Offsite Concentration (mg/m3)c


ERPG-1d (mg/m3)c


ERPG-2d (mg/m3)c


ERPG-3d (mg/m3)c
Arsenic1.03E+03 4.5E-012.8E-04 6.00E-011.00E+00 1.00E+02
Benzene3.0E+03 6.7E+024.2E-01 1.60E+011.60E+02 9.58E+03
Beryllium1.0E+01 4.4E-032.8E-06 5.00E-031.00E-02 1.00E+01
Cadmium6.0E+03 2.7E+001.7E-03 1.50E-012.50E-01 5.00E+02
Chromium6.1E+03 2.7E+001.7E-03 1.50E+002.50+00
(e)
Lead3.6E+05 1.6E+021.0E-01 1.50E-012.50E-01 7.00E+02
Mercury3.4E+04 1.5E+019.4E-03 1.50E-012.00E-01 2.80E+01
Methyl chloride6.5E+02 2.9E+021.8E-01 2.07E+024.13E+02 2.07E+04
Methylethylketone8.0E+03 1.8E+031.1E+00 8.85E+022.95E+03 8.85E+03
Nickel2.8E+01 4.4E-022.8E-05 3.00E+005.00E+00
(e)
Silver1.1E+03 4.7E-013.0E-04 3.00E-015.00E-01
(e)
Trichloroethane7.8E+04 3.5E+022.2E-01 1.91E+035.46E+03 1.64E+04
Xylene3.3E+03 1.6E+019.9E-03 4.34E+028.69E+02 4.34E+03

a. The chemicals presented in this table are those for which concentration guidelines were available.

b. Kilograms. To convert to pounds, multiply by 2.2046.

c. Milligrams per cubic meter of air.

d. Emergency Response Planning Guideline. See Table F-3.

e. No equivalent value found.



Table F-18. Chemical hazards Accidents analysis results for the Organic Waste Storage Tank.




Accident
description


Annual frequency
100-meter concentration (mg/m3)a
640-meter concentration (mg/m3)
Offsite concentration (mg/m3)


ERPG-1b (mg/m3)


ERPG-2 (mg/m3)


ERPG-3 (mg/m3)
Explosion at the OWSTc 2.70E-041.40E+04 6.10E+025.70E+00 1.60E+011.60E+02 9.60E+03
Tornado at the OWST 1.00E-041.02E+04 1.21E+031.54E+01 1.60E+011.60E+02 9.60E+03

a. Milligrams per cubic meter of air.

b. Emergency Response Planning Guideline. See Table F-3.

c. Organic Waste Storage Tank.



Table F-19. Chemical hazards analysis results for the 341-M facility.





Chemical


Inventory (kilograms)a
100-meter concentration (mg/ m)b
640-meter concentration (mg/ m)b
Offsite concentration (mg/ m)b


ERPG-1c (mg/ m)b


ERPG-2c (mg/ m)b


ERPG-3c (mg/ m)b
Sulfuric acid1.52E+04 9.10E-067.70E-07 2.70E-072.00E+00 1.00E+013.00E+01

a. To convert to pounds, multiply by 2.2046.

b. Milligrams per cubic meter of air.

c. Emergency Response Planning Guideline. See Table F-3.



F.5.5 TRANSURANIC AND ALPHA WASTE


The following sections address the impacts of postulated Accidents associated with the alternatives considered in this eis for the management of transuranic and alpha waste.


F.5.5.1 Facilities and Accidents: Transuranic and Alpha Waste

The accident analyses considered all facilities and processes involved in the management of transuranic and alpha waste. The facilities were identified from the transuranic waste information provided in Chapter 2. Table F-20 lists the facilities associated with each of the alternatives. Descriptions of these facilities are provided in Appendix B. For each facility, a list of postulated accident scenarios was developed to support the accident analysis for transuranic waste for each alternative.

Table F-21 lists potential accidents. This information was extracted from the technical reports supporting this eis (WSRC 1994b, c, and e). While all the accidents listed in Table F-21 are supported by quantitative analyses, accident impacts for proposed facilities are not listed in the table because they are mainly qualitative.



Table F-20. Transuranic and alpha waste facilities identified by alternative.


a. Accidents for Resource Conservation and Recovery Act (RCRA) disposal are assumed to be bounded by the accident scenarios associated with the transuranic waste storage pads.

b. Proposed facility.

c. Accidents for the transuranic waste characterization/certification facility are assumed to be the same as the accident scenarios described in the Transuranic Waste Facility Preliminary Safety Analysis Report identified in the WSRC technical report presenting accident analyses for solid wastes (WSRC 1994c).



Table F-21. List of potential accidents associated with the management of transuranic waste.






List of facilities area



No-action alternative


Alternative A (limited treatment configuration)


Alternative C (extensive treatment configuration)
Alternative B
(moderate treatment configuration)
Low-activity waste vaults
X
X
X
X
Transuranic and alpha waste storage pads
X
X
X
X
Experimental Transuranic Waste Assay Facility/ Waste Certification Facility


X
   
RCRA disposala  
X
X
X
Alpha vitrification facilityb   
X
X
Consolidated Incineration Facility   
X
 
Transuranic waste characterization/certification facilityb,c  


X



X



X


No.


Accident description
Annual
frequency
Dosea
(rem)
RiskRisk (rem/yr)
1
Deflagration in culvert during TRUb retrieval activities
1.00E-02
4.56E-01
4.56E-03
2
Fire at the eaV/LAWVc
8.30E-02
3.55E-02
2.95E-03
3
Fire in culvert - TRUb storage pads
8.10E-04
1.94E+00
1.57E-03
4
Drum breach due to culvert overturn during TRU retrieval activities
4.00E-02
2.28E-02
9.12E-04
5
Container breach at the eaV/LAWVc
2.00E-02
4.00E-02
8.00E-04
6
Fire from all causes - TRUb storage pads
2.60E-03
7.52E-02
1.96E-04
7
Vehicular crash - TRUb storage pads
2.60E-03
6.84E-02
1.78E-04
8
Drum rupture on the TRUb storage pads (internally induced)
2.10E-02
5.70E-03
1.20E-04
9
Drum breach/fall of unlined drums during TRUb retrieval activities
7.20E-02
1.10E-01
7.92E-05
10
Fire in the TRUb waste characterization/certification facility w/o HEPAd bypass
6.00E-03
9.50E-03
5.70E-05
11
Drum breach/fall during TRUb retrieval activities
4.00E-02
1.10E-03
4.40E-05
12
Multiple drum deflagration during TRUb retrieval activities
1.50E-04
2.30E-02
3.45E-06
13
Vehicle crash/fire on the TRUb storage pads
6.50E-05
3.51E-01
2.28E-05
14
Explosion with fire in the TRUb waste characterization/ certification facility
4.20E-03
9.10E-04
3.82E-06
15
Large fire for entire CIFe
2.34E-04
1.07E-02
2.50E-06
16
Vehicle crash during TRUb retrieval activities
2.00E-04
4.60E-03
9.20E-07
17
Earthquake at CIFe
1.00E-03
2.65E-04
2.65E-07
18
Explosion at CIFe - rotary kiln
1.50E-04
1.57E-03
2.36E-07
19
High winds - TRUb storage pads
3.80E-03
5.50E-05
2.10E-07
20
Drum fire due to vehicle crash during TRUb retrieval activities
5.00E-06
2.30E-02
1.15E-07
21
High velocity straight winds at CIFe
2.00E-02
5.23E-06
1.05E-07
22
Tornado at the eaV/LAWVc
2.00E-05
4.90E-03
9.80E-08
23
Earthquake - TRUb storage pads
2.00E-04
2.28E-04
4.56E-08
24
F2 tornado on TRUb storage pads
4.50E-05
7.00E-04
3.20E-08
25
Explosion at CIFe - backhoe housing
4.00E-04
5.64E-05
2.26E-08
26
Earthquake at the TRUb waste characterization/certification facility
2.00E-04
8.10E-05
1.62E-08
27
High wind at the eaV/LAWVc
1.00E-03
1.50E-05
1.50E-08
28
F3 tornado on TRUb storage pads
8.00E-06
1.50E-03
1.20E-08
29
Fire in the TRUb waste characterization/certification facility w/ HEPAd bypass
6.00E-06
6.52E-04
3.91E-09
30
High winds on the TRUb storage pads
4.00E-05
7.20E-05
2.90E-09
31
Explosion at CIFe - tank farm tank
3.40E-07
5.36E-03
1.82E-09
32
Explosion at CIFe - tank farm sump and dike area
1.90E-07
6.85E-03
1.30E-09
33
Criticality in the TRUb waste characterization/certification facility
1.00E-06
1.29E-03
1.29E-09
34
HEPAd filter bypass in the TRUb waste characterization/certification facility
2.00E-03
1.00E-09
2.00E-12

a. The dose given is for the offsite maximally exposed individual using 99.5 percentile meteorology.

b. Transuranic.

c. E-Area Vaults low-activity waste vault.

d. High efficiency particulate air.

e. Consolidated Incineration Facility.



Table F-22. Representative bounding radiological accidents for transuranic waste under the no-action alternative.


Point estimate of increased risk per yeara
(increased risk of fatal cancers per occurrence)b
Accident consequences
Latent fatal cancers







No.







Accident description






Frequency (per year)




Uninvolved worker at 100 meters
(rem)




Uninvolved worker at 640 meters
(rem)
Offsite maximally exposed individual (rem)




Population within 80 kilometersc
(person-rem)





Uninvolved worker at 100 meters





Uninvolved worker at 640 meters




Offsite maximally exposed individual





Population within 80 kilometers
1Deflagration in culvert during TRUd drum retrieval activities
1.00E-02

(anticipated)
1.12E+023.97E+00 5.72E-022.90E+03 8.96E-04
(8.96E-02)
1.59E-05
(1.59E-03)
2.86E-07
(2.86E-05)
1.45E-02
(1.45E+00)
3Fire in culvert at the TRUd waste storage pads (one TRU drum in culvert) 8.10E-04

(unlikely)

4.74E+021.69E+01 2.43E-011.23E+04 3.07E-04

(3.79E-01)

5.48E-06

(6.76E-03)

9.84E-08

(1.22E-04)

4.98E-03

(6.15E+00)

13Vehicle crash with resulting fire at the TRUd waste storage pads 6.50E-05

(extremely unlikely)
8.59E+013.06E+00 4.40E-022.23E+03 4.47E-06

(6.87E-02)

7.96E-08

(1.22E-03)

1.43E-09

(2.20E-05)

7.25E-05

(1.12E+00)

a. Point estimate of increased risk per year is calculated by multiplying the consequence (dose) ¥ latent cancer conversion factor ¥ annual frequency.

b. Increased risk of fatal cancers per occurrence is calculated by multiplying the consequence (dose) ¥ latent cancer conversion factor.

c. A conservative assumption of 99.5 percentile meteorology was assumed for determining accident consequences for the exposed population within 80 kilometers. A less conservative meteorology (50 percentile) was used to determine the accident consequences for exposed individuals.

d. Transuranic.



Table F-23. Representative bounding radiological accidents for transuranic waste under alternative B.


Point estimate of increased risk per yeara
(increased risk of fatal cancers per occurrence)b
Accident consequences
Latent fatal cancers







No.







Accident description






Frequency (per year)




Uninvolved worker at 100 meters
(rem)




Uninvolved worker at 640 meters
(rem)
Offsite maximally exposed individual (rem)




Population within 80 kilometersc
(person-rem)





Uninvolved worker at 100 meters





Uninvolved worker at 640 meters




Offsite maximally exposed individual





Population within 80 kilometers
1Deflagration in culvert during TRUd drum retrieval activities
1.00E-02
(anticipated)
1.12E+023.97E+00 5.72E-022.90E+03 8.96E-04
(8.96E-02)
1.59E-05
(1.59E-03)
2.86E-07
(2.86E-05)
1.45E-02
(1.45E+00)
3Fire in culvert at the TRUd waste storage pads (one TRU drum in culvert)
8.10E-04
(unlikely)
4.74E+021.69E+01 2.43E-011.23E+04 3.07E-04

(3.79E-01)

5.48E-06

(6.76E-03)

9.84E-08

(1.22E-04)

4.98E-03

(6.15E+00)

13Vehicle crash with resulting fire at the TRUd waste storage pads
6.50E-05
(extremely unlikely)
8.59E+013.06E+00 4.40E-022.23E+03 4.47E-06

(6.87E-02)

7.96E-08

(1.22E-03)

1.43E-09

(2.20E-05)

7.25E-05

(1.12E+00)

a. Point estimate of increased risk per year is calculated by multiplying the consequence (dose) ¥ latent cancer conversion factor ¥ annual frequency.

b. Increased risk of fatal cancers per occurrence is calculated by multiplying the consequence (dose) ¥ latent cancer conversion factor.

c. A conservative assumption of 99.5 percentile meteorology was assumed for determining accident consequences for the exposed population within 80 kilometers. A less conservative meteorology (50 percentile) was used to determine the accident consequences for exposed individuals.

d. Transuranic.



Table F-24. Representative bounding radiological accidents for transuranic waste under alternative C.


Point estimate of increased risk per yeara
(increased risk of fatal cancers per occurrence)b
Accident consequences
Latent fatal cancers







No.







Accident description




Frequency per year

(accident range)




Uninvolved worker at 100 meters
(rem)




Uninvolved worker at 640 meters
(rem)
Offsite maximally exposed individual (rem)




Population within 80 kilometersc
(person-rem)





Uninvolved worker at 100 meters





Uninvolved worker at 640 meters




Offsite maximally exposed individual





Population within 80 kilometers
1Deflagration in culvert during TRUd drum retrieval activities
1.00E-02
(anticipated)
1.12E+023.97E+00 5.72E-022.90E+03 8.96E-04
(8.96E-02)
1.59E-05
(1.59E-03)
2.86E-07
(2.86E-05)
1.45E-02
(1.45E+00)
3Fire in culvert at the TRUd waste storage pads (one TRU drum in culvert) 8.10E-04

(unlikely)
4.74E+021.69E+01 2.43E-011.23E+04 3.07E-04

(3.79E-01)

5.48E-06

(6.76E-03)

9.84E-08

(1.22E-04)

4.98E-03

(6.15E+00)

12Vehicle crash with resulting fire at the TRUd waste storage pads 6.50E-05

(extremely unlikely)
8.59E+013.06E+00 4.40E-022.23E+03 4.47E-06

(6.87E-02)

7.96E-08

(1.22E-03)

1.43E-09

(2.20E-05)

7.25E-05

(1.12E+00)

Explosion at CIFe - tank farm 3.40E-07

(beyond- extremely- unlikely)
1.28E+004.07E-02 7.01E-044.79E+01 1.74E-10

(5.12E-04)

5.54E-12

(1.63E-05)

1.19E-13

(3.51E-07)

8.14E-09

(2.40E-02)

a. Point estimate of increased risk per year is calculated by multiplying the consequence (dose) ¥ latent cancer conversion factor ¥ annual frequency.

b. Increased risk of fatal cancers per occurrence is calculated by multiplying the consequence (dose) ¥ latent cancer conversion factor.

c. A conservative assumption of 99.5 percentile meteorology was assumed for determining accident consequences for the exposed population within 80 kilometers. A less conservative meteorology (50 percentile) was used to determine the accident consequences for exposed individuals.

d. Transuranic.

e. Consolidated Incineration Facility.



F.5.5.2 Accident Analysis for Transuranic and Alpha Waste No-Action Alternative

This section addresses the effects of postulated Accidents associated with the no-action alternative considered for transuranic wastes. The postulated accidents provide a baseline for comparison of the effects of the postulated accidents associated with the other alternatives.


F.5.5.2.1 Impacts from Postulated Radiological Accidents

From the list of potential radiological Accidents presented in Table F-21, the representative bounding accident scenarios were identified for the no-action alternative. Figure F-7 shows the highest-risk accident scenarios for the four frequency ranges. As shown in Figure F-7, the accidents associated with the transuranic waste storage pads and the low-activity waste vaults are scattered over the three highest accident frequency ranges. However, there are no accidents identified in the technical reports for the beyond-extremely-unlikely accident range. Table F-22 lists the representative bounding accidents, accident consequences, and latent fatal cancers for exposed workers and the public.

Accident Scenario 1 -Deflagration in culvert during transuranic drum handling activities: The culverts are concrete containers used to store up to 14 transuranic waste drums. Transuranic waste drum handling activities would require the movement of some culverts and other waste containers to gain access to the waste drums. Because the drums inside a culvert are not vented, a flammable mixture of hydrogen and air could exist (due to the radiolysis of the polyethylene wrappings inside the drum). Ignition of this flammable gas mixture would most likely occur due to a shift in the material while moving the culverts. Although the curie content of the drums inside the culverts is much higher than that in drums stored directly on transuranic waste storage pads, it is assumed that the amount of curies released to the atmosphere due to a drum deflagration inside a culvert would be mitigated somewhat by the culvert. This accident scenario is considered the representative bounding accident for the anticipated accident range.

Accident Scenario 3 -Fire in a culvert at the transuranic and alpha waste storage pads (one drum): Culverts are concrete containers used to store up to 14 transuranic 55-gallon drums. Transuranic drums stored in concrete culverts potentially generate hydrogen gas through radiolytic decomposition of organics that could be in the drums. As a consequence, a fire hazard is associated with the storage of transuranic and alpha waste in drums. A postulated fire in a concrete culvert is assumed to involve only one drum, since other drums are sealed with gaskets and the lids are secured with metal ring clamps.



Figure F-7. Accidents that were analyzed for the no-action alternative for transuranic waste facilities.

Accident Scenario 12 -Vehicle crash with resulting fire at the transuranic waste storage pads: The frequency of a vehicle crash into a transuranic pad impacting waste containers is estimated as
2.60E-03 event per year. Approximately 2.5 percent of vehicle crashes result in fires. Therefore, the frequency of a vehicle crashing into a transuranic pad and causing a fire is estimated to be 6.50E-05 event per year. It is estimated that a vehicle crash into a transuranic pad followed by a fire would affect 7 pallets (28 drums) of transuranic waste.


F.5.5.2.2 Impacts from New or Proposed Facilities

Table F-20 identifies no new or proposed facilities under the no-action alternative for transuranic waste.


F.5.5.3 Accident Analysis for the Transuranic and Alpha Waste Under Alternative B

This section addresses the impacts of postulated Accidents associated with alternative B considered for the transuranic waste stream.


F.5.5.3.1 Impacts from Postulated Radiological Accidents


This section presents potential effects from postulated radiological Accidents at facilities identified in Table F-20 for alternative B. Figure F-8 shows the highest-risk accident scenarios for the four frequency ranges. As shown in Figure F-8, this alternative consists of many more accident scenarios than the no-action alternative. There are no accidents listed in the technical reports for the beyond-extremely-unlikely accident range. Table F-23 lists the representative bounding accidents, accident consequences, and latent fatal cancers for exposed workers and the public. Although alternative B has additional facilities associated with it, the representative bounding radiological accident scenarios are the same as those for the no-action alternative (Table F-23). However, DOE assumes that the conclusions regarding the representative bounding accident scenarios could be affected by alternative B minimum, maximum, and expected waste forecasts. The accident analyses for the accident scenarios are based on a conservative assumption of peak utilization of facilities, [i.e., the minimum, maximum, and expected waste forecasts would only affect how long the facilities (e.g., the Experimental Transuranic Waste Assay Facility/Waste Certification Facility), would operate]. Therefore, while consequences or frequencies for postulated accidents do not change, the expected duration of risk from a facility-specific accident scenario could be longer or shorter, depending on the case. However, the number of new facilities needed to meet the transuranic waste management requirements could be affected by the minimum, maximum, and expected waste forecasts. Thus, the consequences or frequencies for specific accident scenarios could be increased or decreased, depending on the case. Impacts for these cases are addressed in the representative bounding accident descriptions in Section F.5.5.2.1.

Figure F-8.

Under the expected waste forecast, 14 additional transuranic and alpha waste storage pads would be required. However, for the minimum waste forecast (6 additional transuranic and alpha waste storage pads), it could be assumed that the frequency of this accident scenario occurring would be less than the expected waste forecast, because fewer containers are at risk due to a deflagration. For the maximum waste forecast (1,173 additional transuranic and alpha waste storage pads), it could be assumed that the frequency of this accident scenario occurring would be much greater than the expected waste forecast, because a great many more containers are at risk due to a deflagration.

Accident Scenario 3 -Fire in transuranic culvert at the transuranic and alpha waste storage pads (one transuranic drum): This accident scenario is detailed in Section F.5.5.2.1 and is considered the representative bounding accident for the unlikely accident range.

Accident Scenario 12 -Vehicle crash with resulting fire at the transuranic and alpha waste storage pads: This accident scenario is detailed in Section F.5.5.2.1 and is considered the representative bounding accident for the extremely unlikely accident range. Impacts regarding the alternative B minimum, maximum, and expected waste forecasts would be similar in terms of decreasing and increasing risk, as discussed in the preceding representative bounding accident description.


F.5.5.3.2 Impacts from New or Proposed Facilities

Table F-20 identifies one proposed facility for which quantitative or qualitative accident analyses do not exist. This facility is described below. Because the facility is proposed and its design is not complete, quantitative analyses at this point would provide non-meaningful risk information (because the design could be changed) that could be compared to the risk information available for existing facilities. However, DOE will perform quantitative analyses throughout the design, construction, and operation phases of proposed facilities in accordance with requirements, and DOE will ensure that the risks associated with operating these facilities are within established regulatory guidelines.

Alpha vitrification facility -The alpha vitrification facility would prepare waste for vitrification, vitrify it, and treat the secondary waste gases and liquids generated by the vitrification process. The waste would include newly generated alpha-contaminated waste and mixed waste, alpha-contaminated waste and mixed waste in storage, and some mixed waste soils. This waste would fall in the following treatability groups: 10 to 100 nanocuries per gram nonmixed; 10 to 100 nanocuries per gram mixed; and greater than 100 nanocuries per gram transuranic waste. All waste would enter this facility in drums transported from the transuranic waste characterization/certification facility. The final vitrified and low-temperature stabilized waste forms would be sent back through the transuranic waste characterization/ certification facility for final certification. The vitrification facility would consist of a thermal pretreatment unit, a melter, an afterburner, and an offgas treatment unit. The afterburner would enhance destruction of any remaining hazardous organic compounds prior to treatment in the offgas system. The offgas system would scrub the gases and minimize the release of any hazardous materials or particulates to the atmosphere. It can be assumed that the Accidents initiated by the alpha vitrification facility would be similar to those for the Defense Waste Processing Facility vitrification facility. However, the releases would be minor in comparison. It is also assumed that the offgas treatment unit accidents would be similar to those for the F/H-Area Effluent Treatment Facility.


F.5.5.4 Accident Analysis for Transuranic and Alpha Waste Under Alternative A

The facilities under alternative A are identical to the facilities identified to support alternative B, except that alternative A does not include the alpha vitrification facility. Because the alpha vitrification facility is a proposed facility and as such did not contribute to the representative bounding Accidents , it is assumed that the impacts from the postulated radiological scenarios for alternative A are the same as described in Section F.5.5.3.


F.5.5.5 Accident Analysis for Transuranic and Alpha Waste Under Alternative C

This section addresses the impacts of the postulated Accidents associated with alternative C considered for the transuranic waste stream.

This section presents potential effects from postulated radiological Accidents at facilities identified in Table F-20 for alternative C. Figure F-9 shows the highest risk accident scenarios for the four frequency ranges. As shown in Figure F-9, this alternative consists of many more accident scenarios than the no-action alternative, with a substantial addition of accidents in the unlikely and beyond-extremely-unlikely accident frequency ranges. Table F-24 lists the representative bounding accidents, accident consequences, and latent fatal cancers for exposed workers and the public. DOE assumes that the conclusions regarding the representative bounding accident scenarios could be affected by alternative C minimum, maximum, and expected waste forecasts. The accident analyses for the accident scenarios are based on the conservative assumption of peak utilization of facilities [i.e., the minimum, maximum, and expected waste forecasts would only affect how long the facilities (e.g., Experimental Transuranic Waste

Figure F-9.

Assay Facility/Waste Certification Facility) would operate]. Therefore, while consequences or frequencies for postulated Accidents do not change, the expected duration of risk from a facility-specific accident scenario could be longer or shorter, depending on the case. However, the number of new facilities needed to meet the transuranic waste management requirements could be affected by the minimum, maximum, and expected waste forecasts. Impacts for these cases are addressed in the representative bounding accident descriptions.

Accident Scenario 1 -Deflagration in culvert during drum handling activities. This accident scenario is detailed in Section F.5.5.3.1 and is considered the representative bounding accident for the anticipated accident range.

Accident Scenario 3 -Fire in transuranic culvert at the transuranic and alpha waste storage pads (one transuranic drum): This accident scenario is detailed in Section F.5.5.2.1 and is considered the representative bounding accident for the unlikely accident range.

Accident Scenario 12 -Vehicle crash with resulting fire at the transuranic and alpha waste storage pads: This accident scenario is detailed in Section F.5.5.2.1 and is considered the representative bounding accident for the extremely unlikely accident range. Impacts regarding alternative B minimum, maximum, and expected waste forecasts would be similar in terms of decreasing and increasing risk, as discussed in the preceding representative bounding accident description.

Accident Scenario 31 -Explosion of tanks associated with the Consolidated Incineration Facility: This accident scenario is detailed in Section F.5.2.3.1 and is considered the representative bounding accident for the beyond extremely unlikely accident range.


F.5.5.6 Impacts to Involved Workers from Accidents Involving Transuranic and Alpha Waste

While it is not a representative bounding accident in this analysis, a criticality in the transuranic waste characterization/certification facility could be the most dangerous accident scenario for the involved worker. Direct radiation could affect personnel in the facility, depending on their proximity to the accident location and the degree of shielding in place. Potentially lethal radiation doses (approximately 400 rem) could be received by a person about 7 meters (23 feet) from an unshielded event producing 2.0E+17 fissions. Because 2.0E+18 fissions are assumed for a criticality in the transuranic waste characterization/certification facility, it is estimated that the dose at 7 meters (23 feet) would be approximately 4,000 rad. The 12-inch-thick concrete walls of the waste preparation cell would reduce the radiation dose by a factor of approximately 10, although cell windows would probably provide less protection. Personnel adjacent to the walls of the waste preparation cell could receive fatal doses.

If the high efficiency particulate air filters were bypassed, as assumed in the transuranic waste characterization/certification facility fire scenario, the combustion products would be exhausted to the atmosphere via the sand filter. Thus, DOE assumes no fatalities to workers from radiological consequences. Additionally, operators in the waste preparation cell of the transuranic waste characterization/certification facility would be equipped with respiratory protection and would follow facility-specific and SRS safety procedures.

Accident scenarios involving transuranic waste drum retrieval operations are not expected to result in serious injury or fatalities to involved workers due to radiological consequences. There would be a containment structure for the vent and purge station to protect workers from injury due to a deflagration in a waste drum. Portable air monitors would be required for this operation, in addition to a contamination control hut with a carbon high efficiency particulate air filter exhaust, which would prevent serious injury to adjacent workers due to exposure. Workers inside the contamination hut would be required to wear protective equipment, including respirators, when there is a potential for an airborne contamination.


F.5.5.7 Impacts from Transuranic and Alpha Waste Chemical Accidents

A chemical hazards analysis was performed for the transuranic and alpha waste storage pads. For a discussion of the hazard analysis methodology, refer to Section F.4.2. In the hazards assessment document prepared for the transuranic waste storage pads, specific Accidents were not analyzed. Instead, the entire quantity of chemicals in each segment was assumed to be released. Table F-25 lists the results of this chemical assessment. Because the concentrations do not exceed the ERPG-1 limits, no further analyses were performed. The preliminary chemical hazards analysis performed in conjunction with the initial hazard categorization of the transuranic and alpha waste storage pads provides a bounding chemical analysis for the transuranic and alpha waste. The transuranic waste storage pads are representative of the entire transuranic and alpha waste inventory contained in E-Area. Other facilities such as the transuranic waste characterization/certification facility, alpha vitrification facility, and transuranic waste retrieval activities involve the manipulation of the transuranic and alpha waste inventory, including chemicals contained on the transuranic and alpha waste storage pads.

While the chemical analysis did not address frequencies associated with chemical releases, some qualitative statements concerning the frequency of chemical releases can be made. Because the chemical inventory contained on the transuranic and alpha waste storage pads is widely dispersed, it is difficult to identify a credible accident scenario that could liberate the entire or even a large portion of the chemical inventory. More probable are the accident scenarios identified in Section F.5.3, which would release small amounts of hazardous chemicals along with radionuclides.

A chemical hazards analysis was performed for the Consolidated Incineration Facility. The results of this analysis are described in Section F.5.4.7.



Table F-25. Transuranic and alpha waste storage pads chemical hazards analysis results.





Chemical


Quantity (kg)b
Onsite concentration
100 meters (328 feet) (mg/m3)
c
Offsite concentration (mg/m3)c


ERPG-1d (mg/m3)c


ERPG-2d (mg/m3)c


ERPG-3d (mg/m3)c
Beryllium3.74E+04 1.67E+018.23E-03 5.00E-031.00E-02 1.00E+01
Cadmium7.50E+05 3.33E+021.65E-01 1.50E-012.50E-01 5.00E+01
Chloroform3.75E+04 8.33E+034.11E+00 1.47E+024.88E+02 4.88E+03
Chromium3.75E+04 1.67E+018.23E-03 1.50E-012.50E+00
(e)
Copper1.50E+05 6.67E+013.29E-02 3.00E+005.00E+00
(e)
Lead1.50E+06 6.67E+023.29E-01 1.50E-012.50E-01 7.00E+02
Lead nitrate3.75E+04 1.67E+018.23E-03 1.50E-012.50E-01 7.00E+02
Mercuric nitrate3.75E+04 1.67E+018.23E-03 1.50E-012.00E-01 2.80E+01
MercuryMercury3.75E+04 1.67E+018.23E-03 1.50E-012.00E-01 2.80E+01
Methyl isobutyl ketone 3.75E+041.67E+02 8.23E-023.07E+02 1.02E+031.23E+04
Nickel nitrate3.75E+04 1.67E+018.23E-03 3.00E+005.00E+00
(e)
Silver nitrate3.75E+04 1.67E+018.23E-03 3.00E-015.00E-01
(e)
Sodium chromate3.75E+04 1.67E+018.23E-03 1.50E-012.50E-01 3.00E+01
Toluene3.75E+04 8.33E+034.11E+00 3.77E+027.54E+02 7.54E+03
Trichlorotrifluoro-ethane 3.75E+041.67E+01 8.23E-039.58E+03 1.15E+043.45E+04
Uranyl nitrate3.75E+04 1.67E+018.23E-03 1.50E-012.50E-01 3.00E+01
Xylene3.75E+04 1.67E+028.23E-02 4.34E+028.69E+02 4.34E+03
Zinc3.75E+04 1.67E+018.23E-03 3.00E+015.00E+01
(e)
Zinc nitrate3.75E+04 1.67E+018.23E-03 3.00E+015.00E+01
(e)

a. The chemicals presented in this table are those for which concentration guidelines were available.

b. Kilograms. To convert to pounds, multiply by 2.2046.

c. Milligrams per cubic meter of air.

d. Emergency Response Planning Guideline. See Table F-3.

e. No equivalent value found.



Table F-26. Conservative estimate of risk from seismic accidents.


 
High-level wastea
Hazardous and mixed wasteb
Low-level wastec
Transuranic wasted
 
Accident number
Risk
(rem/yr)
Accident number
Risk
(rem/yr)
Accident number
Risk
(rem/yr)
Accident number
Risk
(rem/yr)
 
3
1.63 E-05
6
9.30E-05
14
2.65E-07
17
2.65E-07
 
13
6.82E-07
11
1.17E-05
 
 
23
4.56E-08
 
27
6.76E-09
13
3.30E-06
 
 
26
1.62E-08
 
28
5.54E-09
20
2.65E-07
 
 
 
 
 
33
1.88E-09
26
3.08E-08
 
 
 
 
 
34
1.54E-09
36
5.54E-09
 
 
 
 
 
40
5.00E-10
37
1.88E-09
 
 
 
 
 
56
7.71E-11
39
1.54E-09
 
 
 
 
 
66
1.38E-11
41
5.00E-10
 
 
 
 
 
 
 
48
7.71E-11
 
 
 
 
 
 
 
53
2.34E-11
 
 
 
 
 
 
 
56
1.38E-11
 
 
 
 
 
 
 
 
 
 
 
 
 
Total seismic risk
 
1.70E-05
 
1.08E-04
 
2.65E-07
 
3.27E-07
Highest risk accident
 





1.91E-04
 





5.26E-03
 





5.20E-03
 





4.56E-03

a. See Table F-4.

b. See Table F-14.

c. See Table F-9.

d. See Table F-21.



F.6 Cumulative Impacts from Postulated Accidents


A severe seismic event was identified as the only reasonably foreseeable accident that has the potential to initiate simultaneous releases of radioactive or toxic materials from multiple facilities at SRS. A design-basis earthquake, which has an estimated ground acceleration of 0.2 times the acceleration of gravity (0.2g) potentially could impact multiple facilities. An earthquake of this magnitude is estimated to have a 2.0 × 10-4 annual probability of occurrence (1 in 5,000 years). Analyses estimating the cumulative impacts from multiple facility releases caused by a severe earthquake at SRS have not been included in the list of potential Accidents (Tables F-4, F-9, F-14, and F-21). Such analyses would be based on the assumption that the earthquake breaches all of the buildings and their materials are released. Even accounting for release fractions and taking credit for existing facility design parameters, this type of analysis is considered too conservative because it is not expected that an earthquake of 0.2g would cause equivalent amounts of damage at multiple locations. Trying to realistically estimate impacts from multiple facilities at different locations would inherently include a margin of error of sufficient magnitude to compromise the confidence in the resulting estimate.

The illustration below is based on the unlikely assumption that an earthquake would cause each postulated accident scenario initiated by an earthquake to occur simultaneously. However, the analysis shows that the cumulative risk of these simultaneous Accidents would be less than the highest-risk accident (Table F-26). Table F-26 lists the risk of each earthquake-initiated accident and the sum of those risks. The highest-risk event is more than 10 times the cumulative seismic-event risk for each corresponding waste type.

The synergistic effects of chemical hazards from simultaneous releases from a common accident initiator were not evaluated due to the scarcity of information about the effects of concurrent exposure to various chemical combinations. DOE is not aware of synergistic effects resulting from simultaneous exposures to radiation and a carcinogenic chemical, such as benzene, each of which is known to result in an increased incidence of cancer. Indeed, synergistic effects of radiation and other agents have been identified in only a few instances, most notably the combined effects of radiation exposure and smoking causing lung cancer among uranium miners. Radioactivity released simultaneously with hazardous chemicals could affect the clean-up or mitigation of the resulting hazard that could have a greater impact than if the releases were separate.


F.7 Secondary Impacts from Postulated Accidents


The primary focus of accident analyses performed to support the operation of a facility is to determine the magnitude of the consequences of postulated-accident scenarios on public and worker health and safety. DOE recognizes that Accidents involving releases of materials can also adversely affect the surrounding environment. To determine the greatest impact that could occur to the environment from the postulated accidents, DOE evaluated each radiological accident scenario to determine potential secondary impacts.


F.7.1 BIOTIC RESOURCES


The consequences of a postulated accident on biotic resources have not been studied. DOE believes that the area of contamination from the postulated-accident scenarios would be localized. Terrestrial biota in or near the contaminated area could be exposed to small quantities of radioactive materials and ionizing radiation until the affected areas could be decontaminated. Effects on aquatic biota would be minor, since no waste management facilities are near any major bodies of water.


F.7.2 WATER RESOURCES


No adverse impacts on water quality from the postulated-accident scenarios are considered likely. Contamination of the groundwater or surface water due to the postulated releases would be minor. Contamination would migrate slowly to the groundwater, so the clean-up efforts that would follow a release incident would capture the contaminants before they reached groundwater.


F.7.3 ECONOMIC IMPACTS


With the exception of the economic effects generated by severe-accident scenarios, such as those initiated by severe earthquakes, limited economic effects would occur as a result of accident scenarios postulated in this appendix. Clean-up of contamination would be localized at the facility where the accident occurred, and DOE expects that the current workforce could perform the clean-up activities. In addition, DOE expects that offsite contamination would be limited or nonexistent.


F.7.4 NATIONAL DEFENSE


The postulated-accident scenarios considered for SRS waste management facilities would not affect national defense.


F.7.5 ENVIRONMENTAL CONTAMINATION


Contamination of the environment from the postulated Accidents for SRS waste management facilities would be limited to the immediate area surrounding the facility where the accident occurred. It is unlikely that the postulated accidents would result in offsite contamination.


F.7.6 THReaTENED AND ENDANGERED SPECIES


Habitats of Federally listed threatened or endangered species have not been identified in the immediate vicinity of the SRS waste management facilities. Because the accident scenarios postulated in this appendix would result only in localized contamination, DOE does not expect these Accidents to affect threatened or endangered species.


F.7.7 LAND USE


Because the Accidents postulated in this appendix would result in only localized contamination around the facility where an accident occurred, and no measurable offsite contamination is likely, DOE expects no impacts on land use.


F.7.8 TReaTY RIGHTS


The environmental impacts of Accidents postulated in this appendix would be within the SRS boundaries. Because there are no Native American lands within SRS boundaries, treaty rights would not be affected.


F.8 Accident Mitigation


An important part of the accident analysis process is to identify actions that can mitigate consequences from Accidents if they occur. This section summarizes the SRS emergency plan, which governs responses to accident situations that affect SRS employees or the offsite population.

The Savannah River Site Emergency Plan defines appropriate response measures for the management of site emergencies (e.g., radiological or hazardous material Accidents ). It incorporates into one document a description of the entire process designed to respond to and mitigate the consequences of an accident. For example, protective actions guidelines are established for accidents involving chemical releases to keep onsite and offsite exposures as low as possible. Exposure is minimized or prevented by limiting the time spent in the vicinity of the hazard or the release plume, keeping personnel as far from the hazard or plume as possible (e.g., physical barricades and evacuation), and taking advantage of available shelter. Emergencies that could cause activation of this plan or part of it include the following:

- Events (operational, transportation, etc.) with the potential to cause releases above allowable limits of radiological or hazardous materials.

- Events such as fires, explosions, tornadoes, hurricanes, earthquakes, dam failures, etc., that affect or could affect safety systems designed to protect SRS and offsite populations and the environment.

- Events such as bomb threats, hostage situations, etc., that threaten the security of SRS.

- Events created by proximity to other facilities, such as the Vogtle Electric Generating Plant (a commercial nuclear power plant across the Savannah River from SRS) or nearby commercial chemical facilities.

Depending on the types of Accidents and the potential impacts, emergencies are classified into one of several categories in accordance with requirements defined in the DOE 5500 series of orders. Incidents classified as "alerts" are expected to be confined within the affected facility boundary. Measurable impacts to workers outside the facility boundary or members of the public would be expected from incidents classified as alerts. Incidents classified as "Site Area Emergencies" represent events that are in progress or have occurred and involve actual or likely major failures of facility safety or safeguards systems needed for the protection of onsite personnel, the public, the environment, or national security. Because Site Area Emergencies have the potential to impact workers at nearby facilities or members of the public in the vicinity of SRS, these emergency situations require notification of and coordination of responses with the appropriate local authorities. Incidents classified as "General Emergencies" are events expected to produce consequences that require protective actions to minimize impacts to both workers and the public. Under General Emergencies, full mobilization of available onsite and offsite resources is usually required to deal with the event and its consequences.

In accordance with the Savannah River Site Emergency Plan, drills and exercises are conducted frequently at SRS to develop, maintain, and test response capabilities and validate the adequacy of emergency facilities, equipment, communications, procedures, and training. For example, drills for the following accident scenarios are conducted periodically in the facilities or facility areas: facility/area evacuations; shelter protection; toxic gas releases; nuclear incident monitor alarms (which activate following an inadvertent nuclear criticality); fire alarms; medical emergencies; and personnel accountability (to ensure that all personnel have safely evacuated a facility or area following an emergency). Periodic drills are also conducted with the following organizations or groups and independently evaluated by the operating contractor and DOE to ensure that they continue to maintain (from both a personnel and equipment standpoint) the capability to adequately respond to emergency situations: first aid teams; rescue teams; fire wardens and fire-fighting teams; SRS medical and health protection personnel, as well as personnel from the nearby Eisenhower Army Medical Center; SRS and local communications personnel and systems; SRS security forces; and SRS health protection agencies.


F.9 References


ACGIH (American Conference of Governmental Industrial Hygienists), 1992, Threshold Limit Values for Chemical Substances and Physical and Biological Exposure Indices, Cincinnati, Ohio.

AIHA (American Industrial Hygiene Association Emergency Response Planning Guidelines Committee), 1991, Emergency Response Planning Guidelines, American Industrial Hygiene Association, Akron, Ohio.

CFR (Code of Federal Regulations), 1990, 29 CFR 1910.1000, Toxic and Hazardous Substances, Air Contaminants, Subpart Z, pp. 6-33, July.

DOE (U.S. Department of Energy), 1993, Recommendations for the Preparation of Environmental Assessments and Environmental Impact Statements, Office of Environment, Safety and Health (EH­25), Washington D.C., May.

DOE (U.S. Department of Energy), 1994a, Preparation Guide for U.S. Department of Energy Nonreactor Nuclear Facility Safety Analysis Reports, DOE-STD-3009-94, Washington, D.C.

DOE (U.S. Department of Energy), 1994b, Final Supplemental Environmental Impact Statement, Defense Waste Processing Facility, DOE/eis-0082-S, Savannah River Operations Office, Aiken, South Carolina.

EPA (U.S. Environmental Protection Agency), 1987, Emergency Planning for Extremely Hazardous Substances, Technical Guidance for Hazard Analysis, with the Federal Emergency Management Agency and U.S. Department of Transportation, USGP01991 517-003/47004, Washington, D.C., December.

Homann, 1988, Emergency Precaution Information Code (EPICodeTM), Homann Associates, Incorporated, Fremont, California.

ICRP (International Commission of Radiological Protection), 1991, 1990 Recommendations of the International Commission of Radiological Protection, ICRP Publication 60, Annals of the ICRP, 21, 1-3, Pergammon Press, New York, New York.

LLNL (Lawrence Livermore National Laboratories), 1990, Design and Evaluation Guidelines for Department of Energy Facilities Subjected to Natural Phenomena Hazards, UCRL-15910, Lawrence Livermore National Laboratory, Livermore, California.

NAS (National Academy of Sciences), 1985, Emergency and Continuous Exposure Guidance Levels for Selected Airborne Contaminants, Volume 1-7, Committee on Toxicology (Board on Toxicology and Environmental Health Standards, Commission on Life Sciences, National Research Council), National Academy Press, Washington, D.C.

NIOSH (National Institute for Occupational Safety and Health), 1990, NIOSH Pocket Guide to Chemical Hazards, U.S. Department of Health and Human Services, Public Health Service, Centers for Disease Control, Washington, D.C.

WSRC (Westinghouse Savannah River Company), 1992, Toxic Chemical Hazard Classification and Risk Acceptance Guidelines for Use in DOE Facilities, WSRC-MS-92-206, Revision 1, Savannah River Site, Aiken, South Carolina.

WSRC (Westinghouse Savannah River Company), 1993, Hazards Assessment Document, Effluent Treatment Facility - Balance of Plant, WSRC-TR-93-031, Revision 1, Savannah River Site, Aiken, South Carolina, April 12.

WSRC (Westinghouse Savannah River Company), 1994a, Consolidated Annual Training Student Handbook, TICATA00.H0100, Savannah River Site, Aiken, South Carolina.

WSRC (Westinghouse Savannah River Company), 1994b, Liquid Waste Accident Analysis in Support of the Savannah River Waste Management Environmental Impact Statement, WSRC­TR­94­0271, Revision 0, Savannah River Site, Aiken, South Carolina, July.

WSRC (Westinghouse Savannah River Company), 1994c, Solid Waste Accident Analysis in Support of the Savannah River Waste Management Environmental Impact Statement, WSRC­TR­94­0265, Revision 0, Savannah River Site, Aiken, South Carolina, July.

­­­

WSRC (Westinghouse Savannah River Company), 1994d, Savannah River Site Emergency Plan,
Manual 6Q, Savannah River Site, Aiken, South Carolina.

WSRC (Westinghouse Savannah River Company), 1994e, Bounding Accident Determination for the Accident Input Analysis of the SRS Waste Management Environmental Impact Statement,

WSRC-TR-94-046, Revision 1, Savannah River Site, Aiken, South Carolina.

WSRC (Westinghouse Savannah River Company), 1994f, AXAIR89Q Users Manual, WSRC­RP­94­313, Savannah River Site, Aiken, South Carolina.

Previous PageTable Of ContentsList Of FiguresList Of TablesNext Page



NEWSLETTER
Join the GlobalSecurity.org mailing list