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Table A-27
LLNL Site 300 ChemicalInventories for the Selected Facilities^a

Building Number	Chemical	Quantity (pounds)b
801	Ammonia gas	< 100c
	Argon	1,131
	Blaco-Tron TF	2,070
	Cadmium oxide	< 100c
	Chevron Inhibited Insulating Oil	17,600
	DTE 24 Lubricating Oil	2,640
	Hydrogen peroxide	<10c
	Lithium hydride	< 100c
	Nitric acid	< 100c
	Nitrogen	23,405
	Sulfur Hexafluoride	650
	Sulfuric acid	< 1c
823	Freon	580
827	Aluminum	501
	Diesel	63,756
	Ethylene Dichloride	2 gal
	Freon	10 gal
	Methylene Chloride	50 gal
	Toluene	1 gal
834	Trichloroethylene	3,500 gal
836	Diesel	2,156
	Hydraulic Oil, Mobil DTE-25	11,200
	Nitrogen	39,795
850	Diesel	2,310
851	Lead	5,000
	Transformer Oil, Shell Dial-Ax	4,800
854	Nitrogen	15,513
865	Acetone	1,320
	Carbon Dioxide	9,240
	Diesel	30,800
	Freon 113	5,240
	Inhibited Insulating Oil	48,440
	Nalco 2589	1,600
	Nitrogen	40,758
	Oil, Vacuum Pump	880
	Propane	3,720
	Steam Clean Detergent, Kokomis 3F4	880
	Sulfur Hexafluoride	9,850
	Trimsol	1,760
870	Diesel	15,400
877	Diesel	15,400
882	Acetone	880
	Argon	580
	Carbon Dioxide	1,680
	Ethylene Glycol	880
	Glycerin	880
	Kerosene	880
	Methyl Ethyl Ketone	1,320
	Nitrogen	1,314
	Oil, Diesel	1,320
	Oil, DTE Hvy Med	880
	Oil, DTE LT24	880
	Oil, DTE Med 25	880
	Oil, Motor	880
	Oil, Turbine	1,760
	Stoddard Solvent	880
	Trichloroethane	880

^a The chemical inventories presented in this table were obtainedfrom the 1989 data base used to prepare the LLNL Site 300 Hazardous MaterialsManagement Plan for San Joaquin County, and were limited to the selectedfacilities described in Appendix A. This list was updated to reflect July 1991quantities. This extensive list within each facility was reduced further andwas limited to extremely hazardous chemicals greater than 1 lb and all otherchemicals greater than 500 lb. Some chemicals listed in the buildingdescriptions may be used in smaller quantities and may not appear in this table. This list represents typical laboratory chemicals and quantities, and does notrepresent maximum limits. These chemicals and their respective quantities aresubject to change as laboratory experimental requirements change. For totalLLNL Site 300 chemical quantities, please refer to Section 4, Table 4.15-2.
^b Quantities are in pounds unless otherwise noted.
^c Source: LLNL, 1991ae

Table A-28
SNL, Livermore ChemicalInventories for the Selected Facilitiesa,b,c

Building Number	Chemical	Quantity (Pounds)d
906	Acetone	419 gal
	Acetylene	13,975 cu ft
	Ammonia/helium	100 cu ft
	Ammonium compounds	58 oz
	Aniline	500 mL
	Argon	9,300 cu ft
	Butane 100%	768 cu ft
	Carbon dioxide 2% in argon	400 cu ft
	Carbon monoxide	2,690 cu ft
	Chlorine	250 cu ft
	Ethanol	70 gal
	Ethylene compounds	1,300 cu ft
	Fluorine/helium	200 cu ft
	Helium	9,472 cu ft
	Hydrogen	8,900 cu ft
	Kerosene	165 gal
	Methane	5,700 cu ft
	Methanol	76 gal
	Nitric acid	500 mL
	Nitric oxide 99%	204 cu ft
	Nitrogen	6,700 cu ft
	Oxygen	6,580 cu ft
	Premix carbon dioxide	1,500 cu ft
	Propane 99%	1,700 cu ft
	Sulfuric acid	500 mL
907	Methanol	6 gal
	Titanium chloride, tetra-	1,700 mL
910	Ammonium persulfate	200
	Helium	1,360 cu ft
	Lead	150
	Nitrogen	760 cu ft
913	Acrylamide	1,000 g
	Acrylonitrile poly	200 g
	Ammonium compounds	117
	Aniline	500 mL
	Antimony compounds	20
	Argon	1,400 cu ft
	Benzene	2 gal
	Benzyl compounds	0.6 gal
	Cadium 1000 ppm aa standard	600 mL
	Chloroform	7 gal
	Ethyl benzene	3,200 mL
	Formaldehyde	500 mL
	Helium	757 cu ft
	Hydrazine monohydrochloride	250 g
	Hydrogen compounds	177 gal
	Lead compounds	963
	Lithium compounds	133
	Mercury compounds (includes mercuric)	142
	Methanol	31 gal
	Nitrobenzene	500 g
	Nitrogen	2,314 cu ft
	Phenol	1 gal
	Potassium compounds	306
	Sodium compounds	10 342 gal
	Sulfuric acid	7 gal
	Titanium compounds	17
	Toluene diisocyanate, 2-,4-	500 g
	Uranium compounds (includes uranyl)	12
914	Argon 100%	1,000 cu ft
	Helium 100%	3,250 cu ft
	Nitrogen	2,250 cu ft
916	Allyl alcohol	100 mL
	Aniline	500 mL
	Argon	8,800 cu ft
	Arsenic ICP std, 2% HNO3	100 mL
	Benzoyl chloride	1,000 mL
	Helium	5,911 cu ft
	Hydrogen	671 cu ft
	Lithium compounds	17
	Methane	450 cu ft
	Methanol	130 L
	Nitric acid compounds	4 gal
	Nitrogen	8,270 cu ft
	Potassium compounds	45
	Propylene compounds	1,675 g
	Silanee	< 1
	Sodium compounds	92
	Sulfur hexafluoride	700 cu ft
	Sulfuric acid	2 gal
	Sulfuric acid ultra pure	4,000 mL
	Titanium compounds	19
923	Lead	100
966	Argon	3,230 cu ft
	Deuterium	464 cu ft
	Helium	2,954 cu ft
	Nitrogen	4,980 cu ft
972	Nitrogen	4,500 cu ft
976	Argon	5,000 cu ft
	Carbon dioxide	3,000 cu ft
	Copper metal powder	600
	Deuterium	300
	Helium	28,700 cu ft
	Hydrogen	3,000 cu ft
	Nitrogen	21,500 cu ft
	Oxygen	3,000 cu ft
983	Lead	100

^a The chemical inventories presented in this table were limitedto the selected facilities described in Appendix A. This list reflects December1991 quantities. This extensive list within each facility was reduced furtherand was limited to extremely hazardous chemicals greater than 1 lb (or 1 gal, or100 cu ft) and all other chemicals greater than 500 lb (or 55 gal, or 300 cuft). Some chemicals listed in the building descriptions may be used in smallerquantities and may not appear in this table. This list represents typicallaboratory chemicals and quantities, and does not represent maximum limits. These chemicals and their respective quantities are subject to change aslaboratory experimental requirements change. For total SNL, Livermore chemicalquantities, please refer to Section 4, Table 4.15-3.
^b Chemical Inventory Listing, updated October 9, 1991, SandiaNational Laboratories, Livermore, California.
^c Buildings 940 through 944 opened in fiscal year 1992. Thesebuildings will use a variety of chemicals, plating and cleaning solutions, laserdyes, oils, and a variety of hazardous chemicals.
^d Quantities are in lb unless otherwise noted.
^e Silane is used in Building 916 Plasma Laboratory fordepositing silicon layer on materials. These experiments use less than onepound of silane per year.
Source: SNL, Livermore, 1991cd, 1991c

Table A-29
LLNL Livermore SiteEstimated Emission Rates (lb/yr)
Based on 1990 Fuel Usage Data^a,b

Building Number	Total Suspended Particles	SOx	NOx	VOCc	CO
111	28	6	920	49	184
113	28	6	910	49	182
115	6	<2	197	11	40
116	<2	<1	55	3	11
117	4	<1	118	7	24
121	31	8	1,290	69	260
123	9	<2	284	15	57
125	8	<2	262	14	53
131	123	25	4,100	218	820
				1,350d
141	f	f	f	1,400d	f
151	93	19	3,080	163	615
153	14	3	454	25	92
171	12	3	393	21	79
				15d
175	f	f	f	400d	f
176	f	f	f	30d	f
177	3	<1	88	5	18
179	f	f	f	70d	f
191	33	7	1,100	59	220
194	<1	<1	27	<2	6
197	f	f	f	527d	f
212	35	7	1,150	61	229
216	5	<1	158	9	32
217	11	3	350	19	70
218	7	<2	226	12	46
219	5	<1	148	8	30
222	66	14	2,200	115	437
223	5	<2	166	9	34
225	<2	<1	45.0	3	10
226	<2	<1	53	3	11
227	15	3	500	27	100
231	141	29	4,700	250	940
239	11	3	350	19	70
241	25	5.0	830	44	166
243	<2	<1	35	<2	7.0
251	15.0	3.0	302	16	101
253	15.0	3.0	502	27	101
254	<2	<1	35	<2	7.0
255	6	<2	188	10	38
261	14	3	443	24	89
273	3	<1	70	4	14.0
281	11	3	350	19	70
291	6	<2	183	10	38
298	f	f	f	300d	f
310	3	<1	88	5	18
311	11	3	350	19	70
314	5	<1	148	8	30
319	9	<2	273	15	55
321	83	17	2,750	146	550
322	<2	<1	62	4	13
323	<2	<1	55	3	11
326	<2	<1	43	3	9
327	6	<2	175	10	35
331	23	5	764	41	153
332	35	7	1,150	61	227
341	9	<2	284	15	57
343	9	<2	286	16	58
345	6	<2	175	10	35
351	6	<2	186	10	38
361	36	8	1,180	63	236
362	4	<1	114	7	23
363	<2	<1	57	4	12
364	13	3	415	22	84
365	11	3	367	20	74
381	45	9	1,490	79	297
391	6	<2	188	10	38
				15,150e
414	83	17	2,750	146	548
415	5	<1	149	8	30
432	<2	<1	44	3	9
435	11	3	350	19	70
482	10	<2	306	17	62
490	14	3	451	24	92
				9,350d
492	f	f	f	30d
551	12	3	369	20	74
622	17	4	546	29	110
663	8	<2	262	14	53

^a Estimates based on cumbustion sources and AP-42 methods(permitted BAAQMD emissions inventory data).
^b For annual emissions of toxic air pollutants, please refer to Section 5, Table 5.1.8-1.
^c Volatile organic compounds estimates based on combustion sources only(permitted BAAQMD emissions inventory data).
^d Permitted volatile organic compounds emission rates (noncombustion sources).
^eVolatile organic compounds emissions from B-391 include 11,000 lb of Freon, 4000lb of ethanol, and 150 lb of acetone.

Table A-30
LLNL Site 300 EstimatedEmission Rates (lb/yr)Based on 1990 Fuel Usage Dataa,b

Building Number	Total Suspended Particles	SOx	NOx	VOCc	CO
827	229	3	164	2	41
865	94	1	67	1	17
871	24	0	17	0	4
875	38	1	27	0	7
877	9	0	6	0	2

^a Estimates based on combustion sources at AP-92 methods(permitted BAAQMD emissions inventory data).
^b For annual emissions of toxic air pollutants, please refer toSection 5, Table 5.1.8-2.
^c Volatile organic compounds estimate based on combustionsources only (permitted BAAQMD emissions inventory data).

Table A-31
SNL, Livermore EstimatedEmission Rates (lb/yr) Based on 1990 Fuel Usage Data^a,b

Building Number	Total Suspended Particles	SOx	NOx	VOCc	CO
907	29	6	940	60	198
910	29	6	950	51	190
912	9	<2	300	16	80
913	15	3	480	16	96
916	3	<2	200	11	40
968	18	4	580	31	116

^a BAAQMD Emissions Inventory Data, estimates based on combustionsources and AP-42 methods.
^b For annual emissions of toxic air pollutants, please refer toSection 5, Table 5.1.8-3.
^c Volatile organic compounds estimates based on combustionsources only (permitted BAAQMD emissions inventory data).